Citation: Li Qi, Xu Han, Tong Yexiang, Li Gaoren. Pt Tube-in-Tube Arrays as HighPerformance Electrocatalysts for Direct Methanol Fuel Cell[J]. Acta Chimica Sinica, ;2017, 75(2): 193-198. doi: 10.6023/A16070337 shu

Pt Tube-in-Tube Arrays as HighPerformance Electrocatalysts for Direct Methanol Fuel Cell

Li Qi ,
Xu Han ,
Tong Yexiang ^*,, ,
Li Gaoren ^*,,

MOE Laboratory of Bioinorganic and Synthetic Chemistry, KLGHEI of Environment and Energy Chemistry, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China

Corresponding author: Tong Yexiang, sysutong@sina.cn Li Gaoren, ligaoren@mail.sysu.edu.cn
Received Date: 13 July 2016

Fund Project: and Natural Science Foundation of Guangdong Province S2013020012833Project supported by the National Natural Science Foundation of China 51173212

Figures(11)

The Pt tube-in-tube arrays (TTAs) were designed and synthesized by ZnO template-assisted electrodeposition. As a robust integrated 3D electrocatalyst with high utilization rate and fast transport of electroactive species, the Pt TTAs exhibit a high electrochemically active surface area (ECSA) of 64.9 m²/gPt. Compared with Pt NTAs and commercial Pt/C catalyst, the Pt TTAs exhibit much improved electrocatalytic activity and durability for methanol oxidation. In addition, the Pt TTAs as electrocatalysts exhibit superior CO poisoning tolerance. This work shows the significant progress of Pt-based electrocatalysts with high-performance for direct methanol fuel cells.
- Pt,
- electrocatalyst,
- tube-in-tube,
- methanol oxidation,
- electroactivity,
- durability
1. [1]
  Jin, R.; Yang, Y.; Xing, Y.; Chen, L.; Song, S.; Jin, R. ACS Nano 2014, 8, 3664.
2. [2]
  Zhang, G.; Xia, B. Y.; Xiao, C.; Yu, L.; Wang, X.; Xie, Y.; Lou, X. W. Angew. Chem. Int. Ed. 2013, 52, 8643.
3. [3]
  Lou, X. W.; Archer, L. A.; Yang, Z. Adv. Mater. 2008, 20, 3987.
4. [4]
  Wang, Z.; Zhou, L.; Lou, X. W. Adv. Mater. 2012, 24, 1903.
5. [5]
  Hu, J.; Chen, M.; Fang, X.; Wu, L. Chem. Soc. Rev. 2011, 40, 5472.
6. [6]
  Liu, J.; Qiao, S. Z.; Chen, J. S.; Lou, X. W.; Xing, X.; Lu, G. Q. Chem. Commun. 2011, 47, 12578.
7. [7]
  Lai, X.; Halpert, J. E.; Wang, D. Energy Environ. Sci. 2012, 5, 5604.
8. [8]
  Xia, B. Y.; Wu, H. B.; Wang, X.; Lou, X. W. J. Am. Chem. Soc. 2012, 134, 13934.
9. [9]
  Wang, Z.; Luan, D.; Boey, F. Y. C.; Lou, X. W. J. Am. Chem. Soc. 2011, 133, 4738.
10. [10]
  Wang, L.; Tang, F.; Ozawa, K.; Chen, Z.-G.; Mukherj, A.; Zhu, Y.; Zou, J.; Cheng, H.-M.; Lu, G. Q. Angew. Chem. Int. Ed. 2009, 48, 7048.
11. [11]
  Wang, B.; Chen, J. S.; Wu, H. B.; Wang, Z.; Lou, X. W. J. Am. Chem. Soc. 2011, 133, 17146.
12. [12]
  Fan, H. J.; Knez, M.; Scholz, R.; Nielsch, K.; Pippel, E.; Hesse, D.; Zacharias, M.; Gosele, U. Nat. Mater. 2006, 5, 627.
13. [13]
  Lai, X.; Li, J.; Korgel, B. A.; Dong, Z.; Li, Z.; Su, F.; Du, J.; Wang, D. Angew. Chem. Int. Ed. 2011, 50, 2738.
14. [14]
  Cho, W.; Lee, Y. H.; Lee, H. J.; Oh, M. Adv. Mater. 2011, 23, 1720.
15. [15]
  Yang, M.; Ma, J.; Zhang, C.; Yang, Z.; Lu, Y. Angew. Chem. Int. Ed. 2005, 44, 6727.
16. [16]
  Roy, P.; Berger, S.; Schmuki, P. Angew. Chem. Int. Ed. 2011, 50, 2904.
17. [17]
  Deng, M.-J.; Chang, J.-K.; Wang, C.-C.; Chen, K.-W.; Lin, C.-M.; Tang, M.-T.; Chen, J.-M.; Lu, K.-T. Energy Environ. Sci. 2011, 4, 3942.
18. [18]
  Kang, T.-S.; Smith, A. P.; Taylor, B. E.; Durstock, M. F. Nano Lett. 2009, 9, 601.
19. [19]
  Park, M.-H.; Cho, Y.; Kim, K.; Kim, J.; Liu, M.; Cho, J. Angew. Chem. Int. Ed. 2011, 50, 9647.
20. [20]
  Lee, S. B.; Mitchell, D. T.; Trofin, L.; Nevanen, T. K.; Soderlund, H.; Martin, C. R. Science 2002, 296, 2198.
21. [21]
  Zhu, Z. P.; Su, D. S.; Weinberg, G.; Schlogl, R. Nano Lett. 2004, 4, 2255.
22. [22]
  Albu, S.; Ghicov, A.; Aldabergenova, S.; Drechsel, P.; LeClere, D.; Thompson, G.; Macak, J.; Schmuki, P. Adv. Mater. 2008, 20, 4135.
23. [23]
  Peng, Q.; Sun, X. Y.; Spagnola, J. C.; Saquing, C.; Khan, S. A.; Spontak, R. J.; Parsons, G. N. ACS Nano 2009, 3, 546.
24. [24]
  Ben Ishai, M.; Patolsky, F. Angew. Chem. Int. Ed. 2009, 48, 8699.
25. [25]
  Wang, Y.-J.; Zhao, N.; Fang, B.; Li, H.; Bi, X. T.; Wang, H. Chem. Rev. 2015, 115, 3433.
26. [26]
  Rana, M.; Chhetri, M.; Loukya, B.; Patil, P. K.; Datta, R.; Gautam, U. K. ACS Appl. Mater. Interfaces 2015, 7, 4998.
27. [27]
  Ruan, M.; Sun, X.; Zhang, Y.; Xu, W. ACS Catal. 2015, 5, 233.
28. [28]
  Sneed, B. T.; Young, A. P.; Jalalpoor, D.; Golden, M. C.; Mao, S.; Jiang, Y.; Wang, Y.; Tsung, C.-K. ACS Nano 2014, 8, 7239.
29. [29]
  Zhang, C.; Xu, L.; Shan, N.; Sun, T.; Chen, J.; Yan, Y. ACS Catal. 2014, 4, 1926.
30. [30]
  Xie, S.; Choi, S.; Lu, N.; Roling, L. T.; Herron, J. A.; Zhang, L.; Park, J.; Wang, J.; Kim, M. J.; Xie, Z.; Mavrikakis, M.; Xia, Y. Nano Lett. 2014, 14, 3570.
31. [31]
  Zhang, Y.; Hsieh, Y.-C.; Volkov, V.; Su, D.; An, W.; Si, R.; Zhu, Y.; Liu, P.; Wang, J. X.; Adzic, R. R. ACS Catal. 2014, 4, 738.
32. [32]
  Qiu, H.-J.; Shen, X.; Wang, J. Q.; Hirata, A.; Fujita, T.; Wang, Y.; Chen, M. W. ACS Catal. 2015, 5, 3779.
33. [33]
  Zhang, L.; Iyyamperumal, R.; Yancey, D. F.; Crooks, R. M.; Henkelman, G. ACS Nano 2013, 7, 9168.
34. [34]
  Oezaslan, M.; Hasché, F.; Strasser, P. J. Phys. Chem. Lett. 2013, 4, 3273.
35. [35]
  Li, H.; Wu, H.; Zhai, Y.; Xu, X.; Jin, Y. ACS Catal. 2013, 3, 2045.
36. [36]
  Porter, N. S.; Wu, H.; Quan, Z.; Fang, J. Acc. Chem. Res. 2013, 46, 1867.
37. [37]
  Kang, Y.; Li, M.; Cai, Y.; Cargnello, M.; Diaz, R. E.; Gordon, T. R.; Wieder, N. L.; Adzic, R. R.; Gorte, R. J.; Stach, E. A.; Murray, C. B. J. Am. Chem. Soc. 2013, 135, 2741.
38. [38]
  Liu, Y.; Mustain, W. E. J. Am. Chem. Soc. 2013, 135, 530.
39. [39]
  Kang, Y.; Ye, X.; Chen, J.; Cai, Y.; Diaz, R. E.; Adzic, R. R.; Stach, E. A.; Murray, C. B. J. Am. Chem. Soc. 2013, 135, 42.
40. [40]
  Hwang, S. J.; Kim, S.-K.; Lee, J.-G.; Lee, S.-C.; Jang, J. H.; Kim, P.; Lim, T.-H.; Sung, Y.-E.; Yoo, S. J. J. Am. Chem. Soc. 2012, 134, 19508.
41. [41]
  Zhou, W.-P.; An, W.; Su, D.; Palomino, R.; Liu, P.; White, M. G.; Adzic, R. R. J. Phys. Chem. Lett. 2012, 3, 3286.
42. [42]
  Yang, J.; Yang, J.; Ying, J. Y. ACS Nano 2012, 6, 9373.
43. [43]
  Yu, W.; Porosoff, M. D.; Chen, J. G. Chem. Rev. 2012, 112, 5780.
44. [44]
  Tan, T. L.; Wang, L.-L.; Johnson, D. D.; Bai, K. Nano Lett. 2012, 12, 4875.
45. [45]
  Li, Y.; Li, Y.; Zhu, E.; McLouth, T.; Chiu, C.-Y.; Huang, X.; Huang, Y. J. Am. Chem. Soc. 2012, 134, 12326.
46. [46]
  Kang, Y.; Pyo, J. B.; Ye, X.; Gordon, T. R.; Murray, C. B. ACS Nano 2012, 6, 5642.
47. [47]
  Liu, H.-X.; Tian, N.; Brandon, M. P.; Zhou, Z.-Y.; Lin, J.-L.; Hardacre, C.; Lin, W.-F.; Sun, S.-G. ACS Catal. 2012, 2, 708.
48. [48]
  Kang, Y.; Qi, L.; Li, M.; Diaz, R. E.; Su, D.; Adzic, R. R.; Stach, E.; Li, J.; Murray, C. B. ACS Nano 2012, 6, 2818.
49. [49]
  Hong, J. W.; Kang, S. W.; Choi, B.-S.; Kim, D.; Lee, S. B.; Han, S. W. ACS Nano 2012, 6, 2410.
50. [50]
  Yamauchi, Y.; Tonegawa, A.; Komatsu, M.; Wang, H.; Wang, L.; Nemoto, Y.; Suzuki, N.; Kuroda, K. J. Am. Chem. Soc. 2012, 134, 5100.
51. [51]
  Koenigsmann, C.; Santulli, A. C.; Gong, K.; Vukmirovic, M. B.; Zhou, W.; Sutter, E.; Wong, S. S.; Adzic, R. R. J. Am. Chem. Soc. 2011, 133, 9783.
52. [52]
  Wang, L.; Nemoto, Y.; Yamauchi, Y. J. Am. Chem. Soc. 2011, 133, 9674.
53. [53]
  Wang, L.; Yamauchi, Y. Chem. Mater. 2011, 23, 2457.
54. [54]
  Zhang, H.; Jin, M.; Wang, J.; Li, W.; Camargo, P. H.; Kim, M. J.; Yang, D.; Xie, Z.; Xia, Y. J. Am. Chem. Soc. 2011, 133, 6078.
55. [55]
  Xia, B. Y.; Ng, W. T.; Wu, H. B.; Wang, X.; Lou, X. W. Angew. Chem. In. Ed. 2012, 51, 7213.
56. [56]
  Chen, Z.; Waje, M.; Li, W.; Yan, Y. Angew. Chem. In. Ed. 2007, 46, 4060.
1. [1]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
2. [2]
  Yi Zhang , Biao Wang , Chao Hu , Muhammad Humayun , Yaping Huang , Yulin Cao , Mosaad Negem , Yigang Ding , Chundong Wang . Fe–Ni–F electrocatalyst for enhancing reaction kinetics of water oxidation. Chinese Journal of Structural Chemistry, 2024, 43(2): 100243-100243. doi: 10.1016/j.cjsc.2024.100243
3. [3]
  Haodong JIN , Qingqing LIU , Chaoyang SHI , Danyang WEI , Jie YU , Xuhui XU , Mingli XU . NiCu/ZnO heterostructure photothermal electrocatalyst for efficient hydrogen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1068-1082. doi: 10.11862/CJIC.20250048
4. [4]
  Xiaoxiao Huang , Zhi-Long He , Yangpeng Chen , Lei Li , Zhenyu Yang , Chunyang Zhai , Mingshan Zhu . Novel P-doping-tuned Pd nanoflowers/S,N-GQDs photo-electrocatalyst for high-efficient ethylene glycol oxidation. Chinese Chemical Letters, 2024, 35(6): 109271-. doi: 10.1016/j.cclet.2023.109271
5. [5]
  Peng Zhang , Yitao Yang , Tian Qin , Xueqiu Wu , Yuechang Wei , Jing Xiong , Xi Liu , Yu Wang , Zhen Zhao , Jinqing Jiao , Liwei Chen . Interface engineering of Pt/CeO₂-{100} catalysts for enhancing catalytic activity in auto-exhaust carbon particles oxidation. Chinese Chemical Letters, 2025, 36(2): 110396-. doi: 10.1016/j.cclet.2024.110396
6. [6]
  Fenglin Wang , Chengwei Kuang , Zhicheng Zheng , Dan Wu , Hao Wan , Gen Chen , Ning Zhang , Xiaohe Liu , Renzhi Ma . Noble metal clusters substitution in porous Ni substrate renders high mass-specific activities toward oxygen evolution reaction and methanol oxidation reaction. Chinese Chemical Letters, 2025, 36(6): 109989-. doi: 10.1016/j.cclet.2024.109989
7. [7]
  Wenhao Wang , Guangpu Zhang , Qiufeng Wang , Fancang Meng , Hongbin Jia , Wei Jiang , Qingmin Ji . Hybrid nanoarchitectonics of TiO₂/aramid nanofiber membranes with softness and durability for photocatalytic dye degradation. Chinese Chemical Letters, 2024, 35(7): 109193-. doi: 10.1016/j.cclet.2023.109193
8. [8]
  Chunshi He , Linqing Li , Yuanrong Sun , Xuefang Wang , Jie Ren , Jianbo Li . Enhanced durability of a novel thiol-epoxy network thermosets with excellent hygrothermal and chemical resistance. Chinese Chemical Letters, 2025, 36(6): 110905-. doi: 10.1016/j.cclet.2025.110905
9. [9]
  Juhong Zhou , Hui Zhao , Ping Han , Ziyue Wang , Yan Zhang , Xiaoxia Mao , Konglin Wu , Shengjue Deng , Wenxiang He , Binbin Jiang . Strategic modulation of CoFe sites for advanced bifunctional oxygen electrocatalyst. Chinese Journal of Structural Chemistry, 2025, 44(1): 100470-100470. doi: 10.1016/j.cjsc.2024.100470
10. [10]
  Lian Sun , Honglei Wang , Ming Ma , Tingting Cao , Leilei Zhang , Xingui Zhou . Shape and composition evolution of Pt and Pt₃M nanocrystals under HCl chemical etching. Chinese Chemical Letters, 2024, 35(9): 109188-. doi: 10.1016/j.cclet.2023.109188
11. [11]
  Min Song , Qian Zhang , Tao Shen , Guanyu Luo , Deli Wang . Surface reconstruction enabled o-PdTe@Pd core-shell electrocatalyst for efficient oxygen reduction reaction. Chinese Chemical Letters, 2024, 35(8): 109083-. doi: 10.1016/j.cclet.2023.109083
12. [12]
  Miaomiao Li , Mengwei Yuan , Xingzi Zheng , Kunyu Han , Genban Sun , Fujun Li , Huifeng Li . Highly polar CoP/Co₂P heterojunction composite as efficient cathode electrocatalyst for Li-air battery. Chinese Chemical Letters, 2024, 35(9): 109265-. doi: 10.1016/j.cclet.2023.109265
13. [13]
  Jincheng Zhang , Mengjie Sun , Jiali Ren , Rui Zhang , Min Ma , Qingzhong Xue , Jian Tian . Oxygen vacancies-rich molybdenum tungsten oxide nanowires as a highly active nitrogen fixation electrocatalyst. Chinese Chemical Letters, 2025, 36(1): 110491-. doi: 10.1016/j.cclet.2024.110491
14. [14]
  Sumiya Akter Dristy , Md Ahasan Habib , Shusen Lin , Mehedi Hasan Joni , Rutuja Mandavkar , Young-Uk Chung , Md Najibullah , Jihoon Lee . Exploring Zn doped NiBP microspheres as efficient and stable electrocatalyst for industrial-scale water splitting. Acta Physico-Chimica Sinica, 2025, 41(7): 100079-. doi: 10.1016/j.actphy.2025.100079
15. [15]
  Naihong Wang , Longkang Zhang , Yejun Guan , Peng Wu , Hao Xu . Pt confined in Sn-ECNU-46 zeolite for efficient alkane dehydrogenation. Chinese Journal of Structural Chemistry, 2024, 43(4): 100248-100248. doi: 10.1016/j.cjsc.2024.100248
16. [16]
  Fanxin Kong , Hongzhi Wang , Huimei Duan . Inhibition effect of sulfation on Pt/TiO2 catalysts in methane combustion. Chinese Journal of Structural Chemistry, 2024, 43(5): 100287-100287. doi: 10.1016/j.cjsc.2024.100287
17. [17]
  Huijie An , Chen Yang , Zhihui Jiang , Junjie Yuan , Zhongming Qiu , Longhao Chen , Xin Chen , Mutu Huang , Linlang Huang , Hongju Lin , Biao Cheng , Hongjiang Liu , Zhiqiang Yu . Luminescence-activated Pt(Ⅳ) prodrug for in situ triggerable cancer therapy. Chinese Chemical Letters, 2024, 35(7): 109134-. doi: 10.1016/j.cclet.2023.109134
18. [18]
  Jialin Cai , Yizhe Chen , Ruiwen Zhang , Cheng Yuan , Zeyu Jin , Yongting Chen , Shiming Zhang , Jiujun Zhang . Interfacial Pt-N coordination for promoting oxygen reduction reaction. Chinese Chemical Letters, 2025, 36(2): 110255-. doi: 10.1016/j.cclet.2024.110255
19. [19]
  Zimo Peng , Quan Zhang , Gaocan Qi , Hao Zhang , Qian Liu , Guangzhi Hu , Jun Luo , Xijun Liu . Nanostructured Pt@RuOx catalyst for boosting overall acidic seawater splitting. Chinese Journal of Structural Chemistry, 2024, 43(1): 100191-100191. doi: 10.1016/j.cjsc.2023.100191
20. [20]
  Jing Cao , Dezheng Zhang , Bianqing Ren , Ping Song , Weilin Xu . Mn incorporated RuO₂ nanocrystals as an efficient and stable bifunctional electrocatalyst for oxygen evolution reaction and hydrogen evolution reaction in acid and alkaline. Chinese Chemical Letters, 2024, 35(10): 109863-. doi: 10.1016/j.cclet.2024.109863

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(997)
HTML views(182)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142