Citation: Li Ran, Lu Yanying, Lei Kaixiang, Li Fujun, Cheng Fangyi, Chen Jun. Resumption of the Discharged Li-AgVO₃ Primary Batteries for Rechargeable Li-O₂ Batteries[J]. Acta Chimica Sinica, ;2017, 75(2): 199-205. doi: 10.6023/A16070329 shu

Resumption of the Discharged Li-AgVO₃ Primary Batteries for Rechargeable Li-O₂ Batteries

Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education), College of Chemistry, Nankai University;Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300071, China

Corresponding author: Cheng Fangyi, fycheng@nankai.edu.cn.Tel
Received Date: 7 July 2016
Revised Date: 30 September 2016

Fund Project: Ministry of Education 113016AProject supported by the National Natural Science Foundation of China 21322101, 21231005111 Project B12015

Figures(9)

Recycling use is one of the energy and resource saving strategies to dispose depleted batteries, especially primary lithium batteries that employ electrode materials based on expensive and low-abundance elements. In this study, we report in detail the recycling use of discharged Li-AgVO₃ primary battery for rechargeable Li-O₂ battery. We demonstrate that the discharged Li-AgVO₃ cell, in which metallic silver nanoparticles in-situ generated in the vanadium oxide nanowires cathode efficiently catalyze the oxygen reduction/evolution reactions (ORR/OER), can be resumed as rechargeable Li-O₂ cells when they are exposed at O₂ atmosphere. By controlling the discharge depths, we obtained different cathodes that were composed of vanadium oxide nanowires and silver nanoparticles. As the electrode was discharged to a lower voltage, more silver nanoparticles with larger particle size were distributed on the surface of vanadium oxides, as a result of the sequential reduction of Ag⁺ to Ag⁰ and V⁵⁺ to V⁴⁺. Specifically, the average size of formed Ag nanoparticles was 15 nm and 70 nm at ceased discharge voltage of 2.9 V and 2.0 V, respectively, while the formation of V⁴⁺ was observed at discharge voltage lower than 2.3 V. Electrochemical tests indicated that the Li-O₂ cells assembled with the AgVO₃ cathode discharged to 2.3 V (AgVO₃-2.3) exhibited the highest specific capacity (9000 mAh·g_carbon^-1), the lowest overpotential and robust cycling performance (up to 95 cycles at the current density of 300 mA·g_carbon^-1). The remarkable electrochemical performance of the Li-O₂ battery with the AgVO₃-2.3 cathode is attributed to the optimization of amount, size and distribution of generated silver nanoparticles that contribute to high electronic conductivity and abundant active sites for the ORR/OER. A combined analysis of electrochemical impedance spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy confirmed that the AgVO₃-2.3 cathode enables the reversible formation and decomposition of Li₂O₂ with lower charge transfer resistance on discharge and charge. The results presented here would provide new insight into the promising recycling application of depleted primary Li-AgVO₃ batteries in rechargeable high-capacity Li-O₂ batteries.
- silver vanadium oxide,
- silver nanoparticles,
- lithium primary battery,
- Li-oxygen battery,
- recycling use,
- oxygen reduction/evolution
1. [1]
  Takeuchi, K. J.; Marschilok, A. C.; Davis, S. M.; Leising, R. A.; Takeuchi, E. S. Coord. Chem. Rev. 2001, 219, 283.
2. [2]
  Cheng, F.; Chen, J. J. Mater. Chem. 2011, 21, 9841.
3. [3]
  Han, C.; Pi, Y.; An, Q.; Mai, L.; Xie, J.; Xu, X.; Xu, L.; Zhao, Y. Nano Lett. 2012, 12, 4668.
4. [4]
  Liang, S.; Zhou, J.; Pan, A.; Li, Y.; Chen, T.; Tian, Z.; Ding, H. Mater. Lett. 2012, 74, 176.
5. [5]
  Zeng, H.; Wang, Q.; Rao, Y. RSC Adv. 2015, 5, 3011.
6. [6]
  Kang, D. H.; Chen, M.; Ogunseitan, O. A. Environ. Sci. Technol. 2013, 47, 5495.
7. [7]
  Liu, Q.; Xu, J.; Xu, D.; Zhang, X. Nat. Commun. 2015, 6, 7892.
8. [8]
  Armand, M.; Tarascon, J. M. Nature 2008, 451, 652.
9. [9]
  Sen, X.; Guo, Y.; Wan, L. Scientia Sinica Chimica 2011, 41, 1229.
10. [10]
  Zhang, Z.; Li, L.; Ren, Q.; Xu, Q.; Cao, B. Chin. J. Chem. 2016, 34, 631.
11. [11]
  Zhang, Y.; Li, Y.; Xia, X.; Wang, X.; Gu, C.; Tu, J. Sci. China Tech. Sci. 2015, 58, 1809.
12. [12]
  Chen, J.; Cheng, F. Acc. Chem. Res. 2009, 42, 713.
13. [13]
  Wang, Y.; Yi, J.; Xia, Y. Adv. Energy Mater. 2012, 2, 830.
14. [14]
15. [15]
  Cao, Y.; Wei, Z.; He, J.; Zang, J.; Zhang, Q.; Zheng, M.; Dong, Q. F. Energy Environ. Sci. 2012, 5, 9765.
16. [16]
  Cheng, F.; Chen, J. Chem. Soc. Rev. 2012, 41, 2172.
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
  Hu, Y.; Zhang, T.; Cheng, F.; Zhao, Q.; Han, X.; Chen, J. Angew. Chem. Int. Ed. 2015, 54, 4338.
22. [22]
  Zhang, S.; Li, W.; Li, C.; Chen, J. J. Phys. Chem. B 2006, 110, 24855.
23. [23]
  Bao, Q.; Bao, S.; Li, C. M.; Qi, X.; Pan, C.; Zang, J.; Wang, W.; Tang, D. Y. Chem. Mater. 2007, 19, 5965.
24. [24]
  Xu, Y.; Han, X.; Zheng, L.; Wei, S.; Xie, Y. Dalton Trans. 2011, 40, 10751.
25. [25]
  Kirshenbaum, K.; Bock, D. C.; Lee, C. Y.; Zhong, Z.; Takeuchi, K. J.; Marschilok, A. C.; Takeuchi, E. S. Science 2015, 347, 149.
26. [26]
  Wittmaier, D.; Cañas, N. A.; Biswas, I.; Friedrich, K. A. Adv. Energy Mater. 2015, 5, 1500763.
27. [27]
28. [28]
  Kumar, S.; Selvaraj, C.; Scanlon, L. G.; Munichandraiah, N. Phys. Chem. Chem. Phys. 2014, 16, 22830.
29. [29]
  Cui, Q.; Zhang, Y.; Peng, Z. Chem. Res. Chin. Univ. 2016, 32, 106.
30. [30]
  Lu, J.; Cheng, L.; Lau, K. C.; Tyo, E.; Luo, X.; Wen, J.; Miller, D.; Assary, R. S. Nat. Commun. 2014, 5, 4895.
31. [31]
  Park, J. B.; Luo, X.; Lu, J.; Shin, C. D.; Yoon, C. S.; Amine, K.; Sun, Y. K. J. Phys. Chem. C 2015, 119, 15036.
32. [32]
  Rozier, P.; Savariault, J. M.; Galy, J. J. Solid State Chem. 1996, 122, 303.
33. [33]
  Song, J.; Lin, Y.; Yao, H.; Fan, F.; Li, X.; Yu, S. ACS Nano 2009, 3, 653.
34. [34]
  Lim, S. H.; Kim, B. K.; Yoon, W. Y. J. Appl. Electrochem. 2012, 42, 1045.
35. [35]
  Li, F.; Tang, D.-M.; Zhang, T.; Liao, K.; He, P.; Golberg, D.; Yamada, A.; Zhou, H. Adv. Energy Mater. 2015, 5, 1500294.
36. [36]
  Cui, Q.; Zhang, Y.; Ma, S.; Peng, Z. Sci. Bull. 2015, 60, 1227.
37. [37]
  Liu, Q.; Jiang, Y.; Xu, J.; Xu, D.; Chang, Z.; Yin, Y.; Liu, W.; Zhang, X. Nano Res. 2015, 8, 576.
38. [38]
  Shao, X.; Zhang, T.; Wen, Z. Chin. J. Chem. 2017, 35, 35.
39. [39]
1. [1]
  Hao Chen , Dongyue Yang , Gang Huang , Xinbo Zhang . Progress on Liquid Organic Electrolytes of Li-O₂ Batteries. Acta Physico-Chimica Sinica, 2024, 40(7): 2305059-0. doi: 10.3866/PKU.WHXB202305059
2. [2]
  Rui Yang , Hui Li , Qingfei Meng , Wenjie Li , Jiliang Wu , Yongjin Fang , Chi Huang , Yuliang Cao . Influence of PC-based Electrolyte on High-Rate Performance in Li/CrO_x Primary Battery. Acta Physico-Chimica Sinica, 2024, 40(9): 2308053-0. doi: 10.3866/PKU.WHXB202308053
3. [3]
  Shanying Chen , Kangning Huo , Ke Qi , Jingyi Li , Shuxin Li , Yunchao Li . A Novel Colloid Electrophoresis Experiment with the Characteristics of Resource Recycling and Inquiry-Driven Experimental Design. University Chemistry, 2024, 39(5): 274-286. doi: 10.3866/PKU.DXHX202311067
4. [4]
  Zeyu Liu , Wenze Huang , Yang Xiao , Jundong Zhang , Weijin Kong , Peng Wu , Chenzi Zhao , Aibing Chen , Qiang Zhang . Nanocomposite Current Collectors for Anode-Free All-Solid-State Lithium Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2305040-0. doi: 10.3866/PKU.WHXB202305040
5. [5]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
6. [6]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
7. [7]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
8. [8]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 2404023-0. doi: 10.3866/PKU.WHXB202404023
9. [9]
  Tao Wang , Qin Dong , Cunpu Li , Zidong Wei . Sulfur Cathode Electrocatalysis in Lithium-Sulfur Batteries: A Comprehensive Understanding. Acta Physico-Chimica Sinica, 2024, 40(2): 2303061-0. doi: 10.3866/PKU.WHXB202303061
10. [10]
  Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059
11. [11]
  Haoyu Sun , Dun Li , Yuanyuan Min , Yingying Wang , Yanyun Ma , Yiqun Zheng , Hongwen Huang . Hierarchical Palladium-Copper-Silver Porous Nanoflowers as Efficient Electrocatalysts for CO₂ Reduction to C₂₊ Products. Acta Physico-Chimica Sinica, 2024, 40(6): 2307007-0. doi: 10.3866/PKU.WHXB202307007
12. [12]
  Xichen YAO , Shuxian WANG , Yun WANG , Cheng WANG , Chuang ZHANG . Oxygen reduction performance of self?supported Fe/N/C three-dimensional aerogel catalyst layers. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1387-1396. doi: 10.11862/CJIC.20240384
13. [13]
  Zhaoyu Wen , Na Han , Yanguang Li . Recent Progress towards the Production of H₂O₂ by Electrochemical Two-Electron Oxygen Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(2): 2304001-0. doi: 10.3866/PKU.WHXB202304001
14. [14]
  Hao XU , Ruopeng LI , Peixia YANG , Anmin LIU , Jie BAI . Regulation mechanism of halogen axial coordination atoms on the oxygen reduction activity of Fe-N₄ site: A density functional theory study. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 695-701. doi: 10.11862/CJIC.20240302
15. [15]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-0. doi: 10.3866/PKU.WHXB202407005
16. [16]
  Laiying Zhang , Yaxian Zhu . Exploring the Silver Family. University Chemistry, 2024, 39(9): 1-4. doi: 10.12461/PKU.DXHX202409015
17. [17]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
18. [18]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
19. [19]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
20. [20]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(1609)
HTML views(185)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Resumption of the Discharged Li-AgVO3 Primary Batteries for Rechargeable Li-O2 Batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

Resumption of the Discharged Li-AgVO₃ Primary Batteries for Rechargeable Li-O₂ Batteries