Citation: Huang Gang, Chen Yuzhen, Jiang Hailong. Metal-Organic Frameworks for Catalysis[J]. Acta Chimica Sinica, ;2015, 74(2): 113-129. doi: 10.6023/A15080547 shu

Metal-Organic Frameworks for Catalysis

1.
Hefei National Laboratory for Physical Sciences at the Microscale, Department of Chemistry, University of Science and Technology of China, Hefei 230026

Corresponding author: Jiang Hailong, jianglab@ustc.edu.cn
Received Date: 17 August 2015

Fund Project: the Recruitment Program of Global Youth Experts and the Fundamental Research Funds for the Central Universities No. WK2060190026the Natural Science Foundation of Anhui Province No. 1408085MB23the National Natural Science Foundation of China Nos. 21371162, 51301159the 973 Program No. 2014CB931803

Figures(20)

Emerging as a relatively new class of porous materials, metal-organic frameworks (MOFs), possessing diversified, designable and tailorable structures as well as ultrahigh surface area, have captured broad research interest and shown potential applications in many fields in recent years. In particular, MOFs have attracted intensive attention in catalysis. In the first two parts of this review, according to the origin of active sites, for examples, coordinatively unsaturated metal centers, functional organic linkers, functional sites chemically grafted onto the framework, as well as metal complexes or metal nanoparticles (MNPs) encapsulated inside the MOFs, etc., we have summarized the recent progress in heterogeneous catalysis over MOFs and their composites in recent several years. In addition, the MOF-based photocatalysis and electrocatalysis have also been briefly introduced in the subsequent two parts. Finally, the further development and challenge in MOF catalysis are discussed.
- metal-organic frameworks,
- porous materials,
- heterogeneous catalysis,
- photocatalysis,
- electrocatalysis
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沈阳化工大学材料科学与工程学院沈阳 110142