Citation: NIE Xue, CHEN Man-Sheng, YU Jiang-Xi. Synthesis, Crystal Structure, Thermal Stability and Luminescent Properties of Cd(Ⅱ) Complex Constructed from 3,5-Dinitrobenzoic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2704-2708. doi: 10.3969/j.issn.1001-4861.2013.00.395 shu

Synthesis, Crystal Structure, Thermal Stability and Luminescent Properties of Cd(Ⅱ) Complex Constructed from 3,5-Dinitrobenzoic Acid

1.
Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008, China

Received Date: 27 March 2013
Available Online: 26 May 2013
Fund Project: 湖南省自然科学基金(No.13JJ6069) (No.13JJ6069)湖南省教育厅一般项目(No.13C082)资助项目。 (No.13C082)

A new complex [Cd(H₂O)₂(DNBA)(Im)₂](DNBA)·H₂O has been synthesized by H₂DNBA and Im with Cd(Ⅱ), where H₂DNBA =3,5-dinitrobenzoic acid, Im=imidazole. The crystal belongs to orthorhombic system, space group Ccc2. The cell parameters are: a=1.324 99(4) nm, b=1.516 01(5) nm, c=2.789 22(8) nm; V=5.602 7(3) nm³, D_c=1.719 g·cm^-3, Z=8, μ=0.866 mm^-1, F(000)=2 912, final discrepancy factors R₁=0.058 3, wR₂=0.146 4. There are two mononuclear Cd(Ⅱ) complexes in the asymmetric unit of the compound, and where the two Cd(Ⅱ) ions are in the same coordination number. In addition, the luminescent property of 1 is also discussed in the liquid state at room temperature. CCDC: 952035.
- cadmium(Ⅱ) complex;crystal structure;thermal stability and fluorescent property
1. [1]
  [1] Yaghi O M, O′Keeffe M, Ockwig N W, et al. Nature, 2003, 423:705-714
2. [2]
  [2] Rao C N R, Natarajan S, Vaidhyanathan R. Angew. Chem., Int. Ed., 2004, 43:1466-1496
3. [3]
  [3] Eddaoudi M, Moler D B, Li H L, et al. Acc. Chem. Res., 2001, 34:319-330
4. [4]
  [4] Hoskins B F, Robson R. J. Am. Chem. Soc., 1989, 111 (15): 5962-5964
5. [5]
  [5] Zhai Q G, Lu C Z, Wu X Y. Cryst. Growth Des., 2007, 7 (11): 2332-2342
6. [6]
  [6] Pedireddi V R, Varughese S. Inorg. Chem., 2004, 43 (2):450-457
7. [7]
  [7] KANG Hui-Yu (康慧珏), WANG Xiu-Li (王秀丽), LIU Guo-Cheng (刘国成). Chinese Journal of Bohai University: Nat. Sci. (Bohai Daxue Xuebao: Ziran Kexue Ban), 2010, 31 (1):23-25
8. [8]
  [8] ZHU Dun-Ru (朱敦如), WANG Zuo-Xiang (王作祥), SONG Jun (宋军), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2005, 21 (1):128-132
9. [9]
  [9] WEI Tai-Bao (魏太保), ZHANG Qin-Sheng (张勤生), CAO Cheng (曹成), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2011, 27 (7):1291-1294
10. [10]
  [10] WANG Rui-Fen (王瑞芬), ZHANG Jian-Jun (张建军), WANG Shu-Ping (王淑萍), et al. Chinese J. Rare Metals (Xiyou Jinshu), 2000, 24 (5):352-355
11. [11]
  [11] ZHANG You-Ming (张有明), ZHANG Qin-Sheng (张勤生), LIN Qi (林奇), et al. Chem. J. Chinese Universities (Gaodeng Xuexiao Huaxue Xuebao), 2011, 32 (9):2181-2186
12. [12]
  [12] YANG Ying-Qun (杨颖群), CHEN Man-Sheng (陈满生), CHEN Zhi-Min (陈志敏), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2011, 27 (9):1847-1851
13. [13]
  [13] Chen S S, Yang S L, Zhang S P. Chinese J. Struct. Chem., 2011, 30 (12):1758-1764
14. [14]
  [14] Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement; University of Göttingen, Göttingen, Germany, 1997.
15. [15]
  [15] Guo J Y, Zhang T L, Zhang J G, et al. Chinese J. Struct. Chem., 2006, 25 (11):1297-1302
1. [1]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
2. [2]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
3. [3]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
4. [4]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
5. [5]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
6. [6]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
7. [7]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
8. [8]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
9. [9]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
10. [10]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
11. [11]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
12. [12]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
13. [13]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
14. [14]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
15. [15]
  Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
16. [16]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
17. [17]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
18. [18]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
19. [19]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
20. [20]
  Keweiyang Zhang , Zihan Fan , Liyuan Xiao , Haitao Long , Jing Jing . Unveiling Crystal Field Theory: Preparation, Characterization, and Performance Assessment of Nickel Macrocyclic Complexes. University Chemistry, 2024, 39(5): 163-171. doi: 10.3866/PKU.DXHX202310084

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(408)
HTML views(46)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142