Citation: ZHANG Jian-Guo, YIN Xin, WU Jin-Ting, SUN Mou, FENG Jin-Ling, ZHANG Tong-Lai, ZHOU Zun-Ning. Two High-Nitrogen Energetic Salts Based on 3,6-Dihydrazino-1,2,4,5-tetrazine[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2587-2594. doi: 10.3969/j.issn.1001-4861.2013.00.391 shu

Two High-Nitrogen Energetic Salts Based on 3,6-Dihydrazino-1,2,4,5-tetrazine

1.
State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China

Received Date: 22 April 2013
Available Online: 29 August 2013
Fund Project: 国家自然科学基金项目(No.10776002)，爆炸科学与技术国家重点实验室自主课题(No.ZDKT12-03) (No.10776002)，爆炸科学与技术国家重点实验室自主课题(No.ZDKT12-03)教育部新世纪优秀人才支持计划(No.NCET-09-0051)资助项目。 (No.NCET-09-0051)

Two high-nitrogen energetic salts were prepared by reacting 3,6-dihydrazino-1,2,4,5-tetrazine (DHT) and perchloric acid or nitric acid aqueous solution. Their structures have been determined by using X-ray single crystal diffraction method. (DHT)(NO₃)₂ (1) belongs to monoclinic, C2/c space group, a=1.300 0(6) nm, b= 0.834 9(3) nm, c=1.018 7(5) nm, β=118.89(5)°, Z=4; (DHT)(ClO₄)₂(2) belongs to orthorhombic, P2₁2₁2 space group, a=0.980 4(4) nm, b=1.074 7(4) nm, c=0.532 5(2) nm, Z=2. The thermal decomposition was investigated with DSC and TG-DTG measurement. The non-isothermal kinetic parameters of the first exothermic process were studied by applying Kissingers, Ozawa-Doyles and Starinks methods. The critical temperature of thermal explosion and sensitivity properties also have been fully investigated. We can come to the conclusion that the two salts have potential application in sensitive energetic material area. CCDC: 884111, 1; 884112, 2.
- crystal structure;energetic ionic salts;3,6-dihydrazino-1,2,4,5-tetrazine;thermal decomposition;sensitivity
1. [1]
  [1] Liang X, Pu X, Tian A. Chin. J. Org. Chem., 2011, 31:328-335
2. [2]
  [2] HU Yin (胡银), MA Hai-Xia (马海霞), ZHANG Jiao-Qiang (张教强), et al. Chemistry (Huaxue Tongbao), 2010, 73:263 -268
3. [3]
  [3] XU Song-Lin (徐松林), LEI Yong-Peng (雷永鹏), YANG Shi-Qing (阳世清), et al. Chin. J. Energ. Mater. (Hanneng Cailiao) 2006, 14:340-342
4. [4]
  [4] Marcus H J, Remanick A. J. Org. Chem., 1963, 28:2372-2375
5. [5]
  [5] FENG Jin-Ling (冯金玲), ZHANG Jian-Guo (张建国), WANG Kun (王昆), et al. Chem. J. Chinese Universities (Gaodeng Xuexiao Huaxue Xuebao), 2011, 32:1519-1525
6. [6]
  [6] Zhang J G, Liang Y H, Feng J L, et al. Z. Anorg. Allg. Chem., 2012, 638, 1212-1218
7. [7]
  [7] Sinditskii V P, Egorshev V Y, Rudakov G F, et al. Thermochim. Acta, 2012, 535, 48-57
8. [8]
  [8] Huynh M H V, Hiskey M A, Archuleta J G, et al. Angew. Chem. Int. Ed., 2004, 43:5658-5661
9. [9]
  [9] Zhou Y, Long X, Shu Y. Chin. J. Chem., 2010, 28:2123-2129
10. [10]
  [10] Zeng Z, Hyer W S, Twamley B, et al. Synthesis-Stuttgart, 2008, 11:1775-1782
11. [11]
  [11] Wang B Z, Lian P, Liu Q, et al. J. Energ. Mater., 2006, 14: 352-354
12. [12]
  [12] Chavez D E, Hiskey M A, Naud D L. Propell. Explos. Pyrot., 2004, 29:209-215
13. [13]
  [13] Oxley J C, Smith J L, Chen H. Thermochim. Acta, 2002, 384, 91-99
14. [14]
  [14] Oxley J C, Smith J L, Zhang J, et al. Proceedings of the 28th NATAS Annual Conference on Thermal Analysis and Applications. Florida: Orlando, FLa, 2000:287-293
15. [15]
  [15] Gao H, Zeng Z, Twamley B, et al. Chem. Eur. J., 2008, 14: 1282-1290
16. [16]
  [16] Trohalaki S, Zellmer R J, Pachter R, et al. Toxicol. Sci., 2002, 68:498-507
17. [17]
  [17] Hussain S, Mattie D R, Frazier J M. CPIA Publication, 2002, 709:141-153
18. [18]
  [18] Chavez D E, Hiskey M A. J. Energ. Mater., 1999, 17:357-377
19. [19]
  [19] Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structure, University of Göttingen, Germany, 1997.
20. [20]
  [20] Sheldrick G M. SHELXL-97, Program for the Refining of Crystal Structure, University of Göttingen, Germany, 1997.
21. [21]
  [21] Kissinger H E. Anal. Chem., 1957, 29:1702-1706
22. [22]
  [22] Ozawa T. Bull. Chem. Soc. Jpn., 1965, 38:1881-1886
23. [23]
  [23] Starink M J. Thermochim. Acta, 1996, 288:97-104
24. [24]
  [24] Hu Z Q, Liang Y J. Thermochim. Acta, 1988, 123:135-151
25. [25]
  [25] Zhang T L, Hu R Z, Xie Y, et al. Thermochim. Acta, 1994, 244:171-176
26. [26]
  [26] HU Rong-Zu (胡荣祖), GAO Sheng-Li (高胜利), ZHAO Feng-Qi (赵凤起), et al. Thermal Analysis Kinetics. 2nd Ed. (热分析动力学, 2版), Beijing: Science Press, 2008.
27. [27]
  [27] Jaidann M, Roy S, Lussier L S. J. Hazard. Mater., 2010, 176: 165-173
28. [28]
  [28] LIU Zi-Tang (刘自铴), LAO Yun-Liang (劳允亮). Initiating Explosive Experimental (起爆药实验). Beijing: Press of Beijing Institute of Technology, 1995.
1. [1]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
2. [2]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
3. [3]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
4. [4]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
5. [5]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
6. [6]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
7. [7]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
8. [8]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
9. [9]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
10. [10]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
11. [11]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
12. [12]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
13. [13]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
14. [14]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
15. [15]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
16. [16]
  Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
17. [17]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
18. [18]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
19. [19]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
20. [20]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(370)
HTML views(9)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142