Citation: GAO Da-Zhi, WANG Ruo-Xu, YE Fan, SHEN Xuan, XU Yan, ZHU Dun-Ru. Syntheses and Crystal Structures of Two Copper Complexes with Pyridyl-Substituted Phenol Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2438-2444. doi: 10.3969/j.issn.1001-4861.2013.00.384 shu

Syntheses and Crystal Structures of Two Copper Complexes with Pyridyl-Substituted Phenol Ligand

1.
College of Chemistry and Chemical Engineering, State Key Laboratory of Materials-oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China

Received Date: 17 May 2013
Available Online: 9 June 2013
Fund Project: 国家自然科学基金(No.21171093) (No.21171093)南京工业大学材料化学工程国家重点实验室开放课题(KL11-03)资助项目。 (KL11-03)

Two mononuclear copper(Ⅱ) complexes, [CuL(CH₃CN)(ClO₄)]ClO₄(1) and cis-[CuL(NCS)₂]·0.5C₄H₈O₂(2) (L=2-[N,N-di(2-pyridylmethyl)aminomethyl]-6-aldehydo-4-methylphenol) have been synthesized and characterized by UV-Vis, FTIR, ESI-MS, elemental analysis and single crystal X-ray crystallography. Both 1 and 2 crystallize in a monoclinic system. Each copper(Ⅱ) ion locates in a distorted octahedron geometry. As a tetradentate chelating ligand, the Lcoordinates to copper(Ⅱ) ion via two pyridyl Natoms, one Natom of tertiary amine, and one phenol O atom. In 1, an acetonitrile molecule and a perchlorate anion also take part in coordination;while there are two cis-disposed NCS-ions in 2. CCDC: 938954, 1;938955, 2.
- phenol ligand;Cu(Ⅱ) complex;crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142