Citation: CHEN Feng-Juan, ZHU Yong-Ze, ZHU Rui-Lun, LIU Guo-Qi, MA Qian, LI Jie, PENG Wan-Tong, CHEN Guo-Ju, ZENG Zheng-Zhi. Synthesis, DNA-Bonding Properties Study of Mercury(Ⅱ) Complex with Tris[(p-hydroxybenzaldehyde) ethyl]amine[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2561-2567. doi: 10.3969/j.issn.1001-4861.2013.00.382 shu

Synthesis, DNA-Bonding Properties Study of Mercury(Ⅱ) Complex with Tris[(p-hydroxybenzaldehyde) ethyl]amine

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1 Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, College of Chemistryand Chemical Engineering, Lanzhou University, Lanzhou 730000, China;

Received Date: 16 December 2013
Available Online: 19 June 2013

Mercury(Ⅱ) complex with tris [(p-hydroxybenzaldehyde)ethyl]amine has been synthesized and characterized. The crystal and molecular structures of the complex was determined by singlecrystal X-ray diffraction. The interaction of complex with calf thymus DNA was investigated by UV-Vis、fluorescence spectrum and viscosity measurements. Results suggest that complex can bind to DNA via intercalation mode. CCDC: 952313, L; 843072, complex.
- tripodal ligand mercury(Ⅱ) complex;calf thymus DNA;intercalation mode
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沈阳化工大学材料科学与工程学院沈阳 110142