Citation: HU Bing, YAO Xiao-Qiang, XIE Yong-Qiang, ZHANG You-Ming, WEI Tai-Bao. Synthesis, Crystal Structure and Properties of Two Coordination Polymers Constructed by Lanthanide and [5-Amino-1, 3, 4-thiadiazol-2-yl]thioglycolic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2422-2432. doi: 10.3969/j.issn.1001-4861.2013.00.379 shu

Synthesis, Crystal Structure and Properties of Two Coordination Polymers Constructed by Lanthanide and [5-Amino-1, 3, 4-thiadiazol-2-yl]thioglycolic Acid

1.
1 College of Science, Gan Agricultural University, Lanzhou 730070, China;

Received Date: 10 June 2013
Available Online: 7 August 2013
Fund Project: 国家自然科学基金(No.21064006,21161018,21262032) (No.21064006,21161018,21262032)甘肃省自然科学基金(No.1010RJZA018) (No.1010RJZA018)教育部长江学者和创新团队发展计划(IRT1177)资助项目。 (IRT1177)

Two lanthanide(Ⅲ) complexes, [Ln(atma)₃(H₂O)₂]_n have been synthesized (Ln=La (1) and Nd (2);Hatma=[5-amino-1,3,4-thiadiazol-2-yl]thioglycolic acid). The structure of Hatma ligand and complexes 1, 2 have been determined by X-ray structural analysis and the structure parameters were analyzed as follows: Hatma, monoclinic, C2/c, a=2.1419(9) nm, b=0.40076(17) nm, c=1.7500(8) nm, V=1.4950(11) nm³, Z=4;1, triclinic, P1, a=0.8820(3) nm, b=1.2306(4) nm, c=1.2586(4) nm, V=1.2913(7) nm³, Z=2;2, triclinic, P1, a=0.8834(4) nm, b=1.2283(5) nm, c=1.2510(5) nm, V=1.2821(9) nm³, Z=2. These two complexes are isomorphic and have one-dimensional chain and rich hydrogen bonds which result in three-dimensional supramolecular structures. The complexes were determined by IR, TGA, elemental analysis and single crystal X-ray diffraction. The antimicrobial assays indicate that the two complexes show better activities than free ligand Hatma. The promoting effects of the title complexes on rape and wheat growth were also tested preliminarily. CCDC: 902095, Hatma;830535, 1;830536, 2.
- rare earth;coordination polymer;crystal structure;biological activity
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沈阳化工大学材料科学与工程学院沈阳 110142