Citation: ZHANG Chun-Li, QIN Ling, XU Ji-Gui, ZHENG He-Gen. Synthesis, Crystal Structure and Optical Properties of Ni(Ⅱ) Coordination Polymer Constructed by 4, 4’-Biphenyl Imidazole and Isophthalic Acid Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2347-2350. doi: 10.3969/j.issn.1001-4861.2013.00.378 shu

Synthesis, Crystal Structure and Optical Properties of Ni(Ⅱ) Coordination Polymer Constructed by 4, 4’-Biphenyl Imidazole and Isophthalic Acid Ligands

1.
1 School of Chemistry and Life Science, Suzhou University, Suzhou, Anhui 234000, China;

Received Date: 23 May 2013
Available Online: 5 August 2013
Fund Project: 国家自然科学基金(No.91022011) (No.91022011)国家重点基础研究发展计划(No.2010CB923303)资助项目。 (No.2010CB923303)

A 2Dcomplex [Ni(H₂O)(MPA)(4,4'-bibp)]_n (1), based on mixed-ligands, bibp (bibp =4,4'-bisimidazolyl-biphenyl) and H₂MPA (H₂MPA=m-phthalic acid), has been synthesized by hydrothermal method and characterized by elemental analysis, IRspectra, TGA, XRD, and the crystal structure was determined by single-crystal X-ray diffraction. The complex crystallizes in the monoclinic system, space group Pc and features a 2D layered structure. The solid UV-Vis properties of ligands and the complex 1 were studied at room temperature. CCDC: 940196.
- Ni(Ⅱ) coordination polymer;crystal structure;optical properties
1. [1]
  [1] Kurmoo M. Chem. Soc. Rev., 2009,38:1353-1379
2. [2]
  [2] Chun H J, Wang X H, Gao S, et al. Inorg. Chem., 2009,48: 1301-1302
3. [3]
  [3] Zhang M D, Di C M, Zheng H G. Inorg. Chem. Commun., 2013,27:88-91
4. [4]
  [4] Zhang M D, Qin L, Yang H T, et al. Cryst. Growth. Des., 2013,13:1961-1969
5. [5]
  [5] Yang Q X, Chen X Q, Cui J H, et al. Cryst. Growth Des., 2012,12(8):4072-4082
6. [6]
  [6] Yang Q X, Huang L F, Zhang M D, et al. Cryst. Growth Des., 2013,13(2):440-445
7. [7]
  [7] Qin L, Hu J S, Zhang M D, et al. Chem. Commun., 2012,48: 10757-10759
8. [8]
  [8] Allendorf M D, Bauer C A, Bhakta R K, et al. Chem. Soc. Rev., 2009,38:1330-1352
9. [9]
  [9] YANG Juan(杨娟), DAI Jun(戴俊), LI Fei-Fei(李飞飞). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(9): 1605-1611
10. [10]
  [10]Nouar F, Eubank J F, Bousquet T, et al. J. Am. Chem. Soc., 2008,130:1833-1835
11. [11]
  [11]Ono K, Yoshizawa M, Akita M, et al. J. Am. Chem. Soc., 2009,131:2782-2783
12. [12]
  [12]Perry J J, Perman J A, Zaworotko M J. Chem. Soc. Rev., 2009,38:1400-1402
13. [13]
  [13]Ryan P E, Lescop C, Laliberte D, et al. Inorg. Chem., 2009, 48:2793-2807
14. [14]
  [14]Dai F N, Dou J M, He H Y, et al. Inorg. Chem., 2010,49: 4117-4120
15. [15]
  [15]DAI Jun(戴俊), YANG Juan(杨娟), CHEN Xi(陈曦). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(8):1617-1624
16. [16]
  [16]Wang X L, Qin C, Wang E B, et al. Chem. Commun., 2007, 34:4245-4247
17. [17]
  [17]Tonigold M, Lu Y, Mavrandonakis A, et al. Chem.-Eur. J., 2011,17:8671-8673
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沈阳化工大学材料科学与工程学院沈阳 110142