Citation: FENG Xiu-Ling. Synthesis and Crystal Structure of a Sandwich-Type Polyoxometalate Built up of the PW₉ Unit[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2603-2608. doi: 10.3969/j.issn.1001-4861.2013.00.366 shu

Synthesis and Crystal Structure of a Sandwich-Type Polyoxometalate Built up of the PW₉ Unit

FENG Xiu-Ling

1.
College of Chemistry and Chemical Engineering, Huaihua University, Huaihua, Hunan 418008, China

Received Date: 26 February 2013
Available Online: 13 June 2013
Fund Project: 湖南省教育厅(No.12C0839)资助项目。 (No.12C0839)

A sandwich-type polyoxometalate compound built on sandwich-type polyoxoanion {Ni₄(H₂O)₂(PW₉O₃₄)₂}^10-, ethlyenediamine(en) and Ni(Ⅱ) cation, [Ni(en)₂]₂[{Ni(en)₂}{Ni(en)₂H₂O}₂{(PW₉O₃₄)₂Ni₄(H₂O)₂}]·16H₂O(1), has been hydrothermally synthesized and characterized by IR spectrum, single crystal X-ray diffraction analysis, TG/DTG and electrochemical studies. The sandwich polyoxoanions are linked by [Ni(en)₂]²⁺ cations to form a 1D linear structure and the multiform hydrogen bonds in the compound form a 3D supramolecular framework. CCDC: 917320.
- polyoxometalates;crystal structure;thermogravimetric analysis;electrochemical property
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Crystal Structure of a Sandwich-Type Polyoxometalate Built up of the PW9 Unit

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Crystal Structure of a Sandwich-Type Polyoxometalate Built up of the PW₉ Unit