Citation: MA De-Yun, QIN Liang, GUO Hai-Fu, LIU Huang, XU Jun. One-Dimensional Cadmium Coordination Polymer Involving 4’-Hydroxybiphenyl-4-carboxylate and 1, 3-Bis(4-pyridyl)propane Ligands： Structure and Luminescence[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2503-2508. doi: 10.3969/j.issn.1001-4861.2013.00.354 shu

One-Dimensional Cadmium Coordination Polymer Involving 4’-Hydroxybiphenyl-4-carboxylate and 1, 3-Bis(4-pyridyl)propane Ligands： Structure and Luminescence

MA De-Yun ¹ ,
QIN Liang ¹ ,
GUO Hai-Fu ¹ ,
LIU Huang ¹ ,
XU Jun ²

1.
1 School of Chemistry and Chemical Engineering, Zhaoqing University, Zhaoqing, Guangdong 526061, China;

Received Date: 13 April 2013
Available Online: 9 June 2013
Fund Project: 广东省教育厅育苗工程(2012LYM_0134) (2012LYM_0134)国家自然科学基金(No.81202461) (No.81202461)中国博士后基金(2013M531906)资助项目 (2013M531906)

A new 1Dcadmium(Ⅱ) coordination polymer, {[Cd(4',4-Hhbc)₂(bpp)₂]}_n (1, 4',4-Hhbc=4'-Hydroxyl-biphenyl-4-carboxylate, bpp=1,3-bis(4-pyridyl)propane), has been hydrothermally synthesized and structurally characterized by elemental analysis, IRspectroscopy, TGA, powder X-ray diffraction, UV-Vis and single crystal X-ray diffraction. Structural determination reveals that 1 exhibits an interesting 1D chain structure. Solid-state 1 emits the intensely indigotin photoluminescence with fluorescence lifetime of 3.2 ns (440 nm) at room temperature. CCDC: 854723.
- cadmium(Ⅱ) coordination polymer;hydrothermal synthesis;crystal structure;luminescence
1. [1]
  [1] Ma D, Li Y, Li Z. Chem. Commun., 2011,47:7377-7379
2. [2]
  [2] Withersby M A, Blake A J, Champness N R, et al. Inorg. Chem., 1999,38:2259-2266
3. [3]
  [3] Wu C D, Lu C Z, Zhuang H H, et al. J. Am. Chem. Soc., 2002,124:3836-3837
4. [4]
  [4] Liu H, Zhao Y, Zhang Z, et al. Adv. Funct. Mater., 2012,21: 4754-4762
5. [5]
  [5] Hagrman D, Haushalter R P, Zubieta J. Chem. Mater., 1998, 10:2091-2100
6. [6]
  [6] Zhang W, Xiong R G. Chem. Rev., 2012,112:1163-1195
7. [7]
  [7] Braun P V, Osenar P, Tohver V, et al. J. Am. Chem. Soc., 1999,121:7302-7309
8. [8]
  [8] Seo J S, Whang D, Lee H, et al. Nature, 2000,404:982-98
9. [9]
  [9] Ma D, Wang W, Li Y, et al. CrystEngComm, 2010,12:4372-4377
10. [10]
  [10]Reineke T M, Eddaoudi M, Moler D, et al. J. Am. Chem. Soc., 2000,122:4843-4844
11. [11]
  [11]Mahata P, Natarajan S. Inorg. Chem., 2007,46:1250-1258
12. [12]
  [12]Ma L F, Wang L Y, Huo X K, et al. Cryst. Growth Des., 2008,8:620-628
13. [13]
  [13]Ma L F, Wang Y Y, Wang L Y, et al. Eur. J. Inorg. Chem., 2008:693-703
14. [14]
  [14]Huang F P, Tian J L, Chen G J, et al. CrystEngComm, 2010,12:1269-1279
15. [15]
  [15]Zhang F W, Li Z F, Ge T Z, et al. Inorg. Chem., 2010,49: 3776-3788
16. [16]
  [16]Carlucci L, Ciani G, Proserpio D M, et al. CrystEngComm, 2002,4:121-129
17. [17]
  [17]Meng C X, Li D S, Zhao J, et al. Inorg. Chem. Commun., 2009,12:793-795
18. [18]
  [18]Zhu Z B, Lu X W. Chinese J. Struct. Chem., 2010,29:465-470
19. [19]
  [19]Wu W P, Wang J, Lu L, et al. Acta Cryst., 2011,E67:m568
20. [20]
  [20]Ma D Y, Guo H F, Lu K, et al. Z. Anorg. Allg. Chem., 2012,638:992-995
21. [21]
  [21]Bruker. APEXII Software, Version 6.3.1, Bruker AXS Inc, Madison, Wisconsin, USA, 2004.
22. [22]
  [22]Sheldrick G M. Acta Cryst., 2008,A64:112-122
23. [23]
  [23]Zhou J S, Cai J, Wang L, et al. Dalton Trans., 2004:1493-1497
24. [24]
  [24]Cakir S, Naumov P, Bulut I, et al. Acta Cryst., 2001,E57: m431-m432
25. [25]
  [25]Zheng Y, Xu D M, Liu S X. Inorg. Chim. Acta, 1999,294: 163-169
26. [26]
  [26]Yang Y, Zhang L, Liu L, et al. Inorg. Chim. Acta, 2007,360: 2638-2646
27. [27]
  [27]Chen Y C, Wang K B, Wang Y. Chinese J. Struct. Chem., 2009,28(12):1613-1618
28. [28]
  [28]LIU Guang-Xiang (刘光祥), HUANG Rong-Yi (黄荣谊), REN Xiao-Ming (任小明). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(9):1680-1684
29. [29]
  [29]Wang X Q, Cheng J K, Wen Y H, et al. Inorg. Chem. Commun., 2005,8:897-899
30. [30]
  [30]Zheng S L, Tong M L, Tan S D, et al. Organomet., 2001,20: 5319-5325
1. [1]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
2. [2]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
3. [3]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
4. [4]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
5. [5]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
6. [6]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
7. [7]
  Ruiying WANG , Hui WANG , Fenglan CHAI , Zhinan ZUO , Benlai WU . Three-dimensional homochiral Eu(Ⅲ) coordination polymer and its amino acid configuration recognition. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 877-884. doi: 10.11862/CJIC.20250052
8. [8]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
9. [9]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
10. [10]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
11. [11]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
12. [12]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
13. [13]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
14. [14]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
15. [15]
  Linjie ZHU , Xufeng LIU . Synthesis, characterization and electrocatalytic hydrogen evolution of two di-iron complexes containing a phosphine ligand with a pendant amine. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 939-947. doi: 10.11862/CJIC.20240416
16. [16]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
17. [17]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
18. [18]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
19. [19]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
20. [20]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(278)
HTML views(7)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142