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Citation: ZHANG Zhao-Po, WANG Yuan, WU Wei-Na, CAI Hong-Xin. Isostructural Lanthanide Complexes (La, Ce) of Diphenyl-quinolinyloxy Acetamide Ligand: Syntheses, Structures and Fluorescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2239-2244. doi: 10.3969/j.issn.1001-4861.2013.00.340 shu

Isostructural Lanthanide Complexes (La, Ce) of Diphenyl-quinolinyloxy Acetamide Ligand: Syntheses, Structures and Fluorescent Properties

1.
Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo, Henan 454000, China

Received Date: 20 November 2012
Available Online: 20 March 2013
Fund Project: 国家自然科学基金(21001040) (21001040)河南省科技厅基础与前沿研究项目(132200410404) (132200410404)河南省教育厅自然科学基金(12B150011)资助项目 (12B150011)

Two isostructural lanthanide complexes, [LnL₂(NO₃)₃] (L=N,N-diphenyl-2-(quinolin-8-yloxy)acetamide, Ln=La(Ⅲ), 1; Ce(Ⅲ), 2) were synthesized and characterized by X-ray diffraction. In each complex, center metal ion is coordinated to four oxygen and two nitrogen atoms from two independent acetamide ligands and also to six oxygen atoms from three nitrate anions, possessing a coordination geometry closer to a distorted icosahedron. In CH₃CNsolution, both complexes exhibit strong fluorescence emission. CCDC: 941145, 1; 941146, 2.
- amide type ligand; lanthanide complex; fluorescence; crystal structure
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