Citation: CHE Guang-Bo, LI Wei-Wei, WANG Shan-Shan, WANG Dan, ZHAO Han, LIU Chun-Bo. Hydrothermal Syntheses and Crystal Structures of Cd(Ⅱ) and Zn(Ⅱ) Complexes Constructed with 1,4-Benzenedicarboxylic Acid and Imidazo[4,5-f][1,10]phenanthroline Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2188-2194. doi: 10.3969/j.issn.1001-4861.2013.00.337 shu

Hydrothermal Syntheses and Crystal Structures of Cd(Ⅱ) and Zn(Ⅱ) Complexes Constructed with 1,4-Benzenedicarboxylic Acid and Imidazo[4,5-f][1,10]phenanthroline Ligands

1.
1 Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Chinese Ministry of Education, Jilin Normal University, Siping, Jilin 136000, China;

Received Date: 1 December 2012
Available Online: 28 April 2013
Fund Project: 教育部新世纪优秀人才(No.NCET-10-0176)资助项目 (No.NCET-10-0176)

Two novel metal-organic frameworks (MOFs), [Cd(bdc)(Imphen)(H₂O)]_n·nH₂O (1) and [Zn(bdc)(Imphen)(H₂O)]_n·nH₂O (2) based on 1,4-benzenedicarboxylic acid (H₂bdc) and imidazo[4,5-f][1,10]phenanthroline (Imphen) ligands, have been constructed under hydrothermal conditions. The complexes are characterized by elemental analyse, single crystal X-ray diffraction. Structural analyses show that the complexes1 and b>2 all present one dimensional chain and bdc^2- ligands display different coordination modes. Furthermore, the adjacent chains are further connected by the hydrogen-bonding and π-π stacking interactions generating three-dimensional supramolecular structures. In addition, thermal stability and luminescent properties of two complexes were also investigated. CCDC: 947287, 1; 947288, 2.
- cadmium(Ⅱ) complex; zinc(Ⅱ) complex; 1,4-benzenedicarboxylic acid; imidazo[4,5-f][1,10]phenanthroline; crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142