Citation: YANG Chao, LIU Jing-Song, ZHANG Min-Fang, YOU Mei-Rong. Effect of Sintering Temperature on B-Site Order of Pb(Mg_1/3Nb_2/3)O₃-Based Ferroelectric Ceramics[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2145-2149. doi: 10.3969/j.issn.1001-4861.2013.00.334 shu

Effect of Sintering Temperature on B-Site Order of Pb(Mg_1/3Nb_2/3)O₃-Based Ferroelectric Ceramics

1.
State Key Laboratory Cultivation Base for Nonmetal Composite and Functional Materials, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China

Received Date: 19 March 2013
Available Online: 16 May 2013
Fund Project: 四川省教育厅青年基金(No.09ZB095)资助项目 (No.09ZB095)

The effect of CuOdoping on B-site order of 0.94Pb(Mg_1/3Nb_2/3)O₃-0.06PbTiO₃ (abbreviated as PMN-6PT) ceramics with different sintering temperatures was studied. The Raman and XRDresults revealed that under different sintering temperature, ion substitution was different, which had different influence to B-site order. Sintering temperature at 950 ℃, Cu²⁺ ions entered the crystal lattice and made no difference in the B-site order. However, Sintering temperature at 1080 ℃, Cu¹⁺ ions entered the crystal lattice and had an effect in the B-site order. The dependence of dielectric constant on temperature illustrated an obvious relaxor characteristic for CuOdoped PMN-based ceramics, which was in accord with Raman spectra analysis.
- sintering temperature; diffuseness parameter; B-site order; Raman spectra
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Sintering Temperature on B-Site Order of Pb(Mg1/3Nb2/3)O3-Based Ferroelectric Ceramics

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com

Effect of Sintering Temperature on B-Site Order of Pb(Mg_1/3Nb_2/3)O₃-Based Ferroelectric Ceramics