Citation: WANG Yin-Ge, LIU Qian-Qian, ZHAI Li-Xin, QIAN Hui-Fen, HUANG Wei. Structural and Spectral Studies of Cis Cadmium(Ⅱ), Manganese(Ⅱ) and Nickel(Ⅱ) Complexes Having 2-Thiophenimidazo[4,5-f][1,10]phenanthroline and 2-(5-Bromothiophen)imidazo[4,5-f][1,10]phenanthroline Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1687-1695. doi: 10.3969/j.issn.1001-4861.2013.00.294 shu

Structural and Spectral Studies of Cis Cadmium(Ⅱ), Manganese(Ⅱ) and Nickel(Ⅱ) Complexes Having 2-Thiophenimidazo[4,5-f][1,10]phenanthroline and 2-(5-Bromothiophen)imidazo[4,5-f][1,10]phenanthroline Ligands

1.
1College of Sciences, Nanjing University of Technology, Nanjing 210009, China;

Received Date: 16 February 2013
Available Online: 28 May 2013
Fund Project: 国家自然科学基金(No.21171088) (No.21171088)

Three mononuclear cadmium(Ⅱ), manganese(Ⅱ) and nickel(Ⅱ) complexes having 2-thiophenimidazo[4,5-f][1,10]phenanthroline (TIP) and 2-(5-bromothiophen)imidazo[4,5-f][1,10]phenanthroline (5-Br-TIP) ligands formulated as [cis-Cd(NO3)(TIP)₂] (1), [cis-MnCl₂(5-Br-TIP)₂] (2) and [cis-NiCl₂(TIP)₂] (3), have been synthesized and structurally compared. They are characterized by elemental analysis, FT-IR, UV-Vis spectra, luminescence spectra and X-ray single-crystal structural analysis. All of them are 1:2 mononuclear complexes with the same cis configuration, among which complex 1 is eight-coordinated and the others are six-coordinated. Ligands TIP and 5-Br-TIP in complex 1~3 are essentially planar with the dihedral angles between imidazole and thiophene rings in the range of 3.9(1)°~9.2(1)°. CCDC: 922633, 1; 922634, 2; 922635, 3.
- cadmium(Ⅱ) complex;manganese(Ⅱ) complex;nickel(Ⅱ) complex;2-thiophenimidazo[4,5-f][1,10]phenanthroline;2-(5-bromothiophen) imidazo[4,5-f][1,10]phenanthroline;crystal structure
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