Citation: ZUO Luo, FENG Jian-Hua, GUO Li, LI Hui-Hui, WU Gang. Synthesis, Structure, Luminescest and Thermal Stable Properties of 3,4-Pyridinedicarboxylic Acid Barium Complex[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1979-1984. doi: 10.3969/j.issn.1001-4861.2013.00.291 shu

Synthesis, Structure, Luminescest and Thermal Stable Properties of 3,4-Pyridinedicarboxylic Acid Barium Complex

ZUO Luo ¹ ,
FENG Jian-Hua ¹ ,
GUO Li ¹ ,
LI Hui-Hui ¹ ,
WU Gang ^1,2

1.
1 College of Material and Chemical Engineering, Chu Zhou University, Chuzhou, Anhui 239012, China;

Received Date: 23 July 2012
Available Online: 4 May 2013
Fund Project: 安徽省自然科学基金(No.1208085MB31) (No.1208085MB31)安徽省应用化学重点建设学科基金(No.200802187C) (No.200802187C)安徽省化学工程与工艺教学团队 (No.20101035) (No.20101035)滁州学院大学生科研项目(No.2012XS18,2012XS19)资助项目。 (No.2012XS18,2012XS19)

Solvothermal reaction of BaCl₂·2H₂O with 3,4-pyridinedicarboxylic acid afforded a new inorganic-organic hybrid framework,[Ba₂(pdc)₂(H₂O)₃]_n (1) (H₂pdc=3,4-pyridinedicarboxylic acid). This complex has been fully characterized by single crystal X-ray diffraction, elemental analysis, and IR spectrum. X-ray analysis shows that complex 1 features a two-dimensional network (2D). Ba1 takes eight-coordinated distorted square antiprism geometry. Ba₂ takes ten-coordinate distorted dicapped square prism coordination geometry. The whole pdc^2- anion connects four different Ba(Ⅱ) atoms, giving rise to a 2D network structure. The three-dimensional structure is formed by O-H…N hydrogen bonding interactions. Thermal stability and luminescent property of compound 1 have also been investigated. CCDC: 887479.
- Ba(Ⅱ) complex;carboxylate group;luminescent property;thermogravimetry
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