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Citation: TONG Xiao-Qiang, LU Hui-Ying, HUANG Pai, YAN Wen-Fu, YU Ji-Hong, XU Ru-Ren. Synthesis and Characterization of a New Three-Dimensional Open-Framework Aluminophosphate [C4H14N2][Al4P5O19OH] and Investigation of the Structure-Directing Effect[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1639-1644. doi: 10.3969/j.issn.1001-4861.2013.00.281 shu

Synthesis and Characterization of a New Three-Dimensional Open-Framework Aluminophosphate [C4H14N2][Al4P5O19OH] and Investigation of the Structure-Directing Effect

  • 1.

    State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China

  • Received Date: 1 February 2013
    Available Online: 25 April 2013

    Fund Project: 国家自然科学基金(No.21171063) (No.21171063)优秀青年基金(No.21222103) (No.21222103)国家重点基础研究发展规划项目(2011CB808703) (2011CB808703)

  • A new three-dimensional (3D) anionic open-framework aluminophosphate [C4H14N2][Al4P5O19OH] (AlPO-BDA) was hydrothermally synthesized by using 1,4-diaminobutane (BDA, C4H12N2) as a structure directing agent. The structure was determined by single-crystal X-ray diffraction structural analysis. AlPO-BDA was further characterized by powder X-ray diffraction (XRD), scanning electron microscope (SEM), elemental (CHN) and thermogravimetric (TG) analyses. The open-framework of AlPO-BDA contains 12-ring (12R) channels along [010] direction which are intersected with 8-ring (8R) channels running along [100] direction. In the presence of 1, 6-hexanediamine (HDA), 1, 5-pentanediamine (PDA), or 2-methylpentamethylenediamine (MPMD) and under hydrothermal condition, anionic open-frameworks with similar topology of AlPO-BDA can be obtained, which are denoted AlPO-HDA, AlPO-PDA, and AlPO-MPMD, respectively. However, their crystallographic symmetry and the shape of the channels are different. These results suggest that these amines have the same topological structure-directing effect but different structure-directing effect in the formation of these open-frameworks. The correlation between the calculated free volume and surface of the open-frameworks and the N-N distance of the diamines is observed. CCDC: 947284
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