Citation: CHEN Lan-Hua, LI Xuan, GUO Xiang-Ke, GUO Xue-Feng, DING Wei-Ping. Composite-Hydroxide-Assisted Hydrothermal Synthesis of Magnesium Silicate Nanotube[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1333-1338. doi: 10.3969/j.issn.1001-4861.2013.00.277 shu

Composite-Hydroxide-Assisted Hydrothermal Synthesis of Magnesium Silicate Nanotube

1.
Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Received Date: 3 May 2013
Available Online: 29 May 2013
Fund Project: 国家重点基础研究项目(No.2009CB623504) (No.2009CB623504)国家科学自然基金(No.20773062,20773063,21173119,21273109)资助项目。 (No.20773062,20773063,21173119,21273109)

A mild and highly efficient hydrothermal synthesis method for uniform magnesium silicate nanotubes was developed from normal Mg(OH)₂ and SiO₂ powders with the assistance of potassium hydroxide and sodium hydroxide. The samples were characterized by XRD, TEM, IR, and nitrogen adsorption-desorption. The synthetic process was studied by XRD, TEM, etc. The results indicate that the eutectic solution of potassium hydroxide and sodium hydroxide offers higher dissolvability for the reactants and benefits the reaction between the reactants. This composite-hydroxide-assisted approach is a mild and highly efficient procedure for the synthesis of high quality magnesium silicate nanotubes at 250 ℃ in a short duration of 36 hours, while it needs over 7 days at 250 ℃ for traditional hydrothermal method.
- nanotube;hydrothermal synthesis;magnesium silicate;composite-hydroxide;eutectic solution
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沈阳化工大学材料科学与工程学院沈阳 110142