Citation: HU Tuo-Ping, LIU Jian-Feng, LÜ Xu-Yan, XIAO Li-Qun, SONG Jiang-Feng. Syntheses, Crystal Structures and Fluorescent Properties of Two Complexes (Zn(Ⅱ) and Co(Ⅱ)) Based on 2H-Imidazole-4, 5-dicarbonitrile[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1928-1934. doi: 10.3969/j.issn.1001-4861.2013.00.270 shu

Syntheses, Crystal Structures and Fluorescent Properties of Two Complexes (Zn(Ⅱ) and Co(Ⅱ)) Based on 2H-Imidazole-4, 5-dicarbonitrile

1.
Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China

Received Date: 9 October 2013
Available Online: 1 May 2013
Fund Project: 国家国际科技合作(No.2011DFA51980) (No.2011DFA51980)省自然科学基金(No.2011081022)资助项目。 (No.2011081022)

Two novel metal-organic complexes {[Zn₂(IMDN)₄(H₂O)₃]·(H₂O)₃}_n (1) and[Co(IMDN)₂(H₂O)₂]_n (2) (HIMDN=2H-imidazole-4,5-dicarbonitrile) based on HIMDN have been synthesized by the method of normal temperature diffusion, and characterized by elemental analysis, FTIR, thermal gravimetric analysis and X-ray diffraction single-crystal structural analysis. The coordination environment of two Zn (Ⅱ) ions is different in 1. One Zn (Ⅱ) ion is four-coordinated and the other is six-coordinated. The central Co (Ⅱ) ion is six-coordinated in 2. Both complexes show one dimensional (1D) chain structure and connected by hydrogen bonds to form three-dimensional structure. Moreover, the fluorescent property of complex 1 had been investigated in the solid state. CCDC: 889348, 1; 889349, 2.
- 2H-imidazole-4,5-dicarbonitrile;1D chain;crystal structure;fluorescence
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沈阳化工大学材料科学与工程学院沈阳 110142