Citation: GE Chun-Hua, ZHANG Rui, WANG Li-Xia, ZHANG Xiang-Dong, WANG Ying-Qi. Two Solvent-Controlled Copper(Ⅱ) Complexes Constructed from Tris[(benzimidazol-2-yl)methyl]amine and m-Phenylenediaminetetraacetic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1993-1998. doi: 10.3969/j.issn.1001-4861.2013.00.265 shu

Two Solvent-Controlled Copper(Ⅱ) Complexes Constructed from Tris[(benzimidazol-2-yl)methyl]amine and m-Phenylenediaminetetraacetic Acid

1.
College of Chemistry, Liaoning University, Shenyang 110036, China

Received Date: 15 November 2012
Available Online: 19 March 2013
Fund Project: 辽宁省自然科学基金(No.201202093) (No.201202093)辽宁省教育厅创新团队计划(No.LT2012001) (No.LT2012001)

The reactions of tris[(benzimidazol-2-yl)methyl]amine (ntb) and 1,3-phenylenedinitrilotetraacetic acid (H₄mpda) with copper nitrate can produce complex 1 from CH₃COCH₃/CH₃OH/H₂O and complex 2 from DMF/CH₃OH/H₂O. Complexes with the formula of[Cu(ntb)(H₂mpda)]·0.5CH₃COCH₃·2H₂O (1) and[Cu(ntb)(H₂mpda)]·DMF·CH₃OH·2H₂O (2) both have[Cu(ntb)(H₂mpda)] structural units, in which Cu(Ⅱ) centers always have a five-coordination number bound to one ntb ligand and one H₂mpda anion. All these complexes possess trigonal bipyramidal coordination geometry. However, metal ions show remarkable differences in structures due to the effects of solvents. Comparing to complex 1, complex 2 possesses more distorted coordination geometry. The positions of ntb and H₂mpda ligands in 1 and 2 are very different. The mononuclear coordination units are extended by hydrogen-bonding into different three dimensional networks. CCDC: 893363, 1; 893364, 2.
- copper complex;tris[(benzimidazol-2-yl)methyl]amine;1,3-phenylenedinitrilotetraacetic acid;solvent-dependence
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沈阳化工大学材料科学与工程学院沈阳 110142