Citation: JIANG Jing, WANG Dong-Jie, LIU Zhi-Peng, WANG Jun-Long, LI Xing. Synthesis, Crystal Structure and Luminescent Properties of a Cd(Ⅱ) Complex with 1, 3-Di(4-pyridy)propane[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1952-1956. doi: 10.3969/j.issn.1001-4861.2013.00.260 shu

Synthesis, Crystal Structure and Luminescent Properties of a Cd(Ⅱ) Complex with 1, 3-Di(4-pyridy)propane

1.
Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang 315211, China

Received Date: 30 December 2012
Available Online: 7 April 2013
Fund Project: 浙江省自然科学基金(No.LY12B01005) (No.LY12B01005)上海市分子催化和功能材料重点实验室开放课题(No.2012MCIF02) (No.2012MCIF02)

A new Cd(Ⅱ) complex {[CdL₂(H₂O)₂]·2(C₇H₆N₅)}_n(C₇H₆N₅=5-(3-aminophenyl)tetrazole ion) based on a ligand L (L=1,3-di(4-pyridy)propane) has been synthesized and structurally characterized by X-ray single crystal diffraction analysis. Structural analysis reveals that the complex is a one-dimensional complex. The Cd(Ⅱ) ion adopts a distorted octahedral coordinated geometry formed by four N atoms and two O atoms, of which four N atoms from different L ligands, two O atoms from different H₂O. In the crystal, adjacent Cd(Ⅱ) centers are bridged by L ligands to generate a one-dimensional chain structure. The one-dimensional chains are further connected into a three-dimensional supramolecular network by O-H…N, N-H…N hydrogen bonding contacts. CCDC: 908806.
- 1, 3-di(4-pyridy)propane;Cd(Ⅱ) complex;crystal structure;fluorescence
1. [1]
  [1] Noro S, Kitagawa S, Kondo M, et al. Angew. Chem., Int. Ed., 2000,39:2082-2085
2. [2]
  [2] Zaworotko M J. Chem. Soc. Rev., 1994,23:283-288
3. [3]
  [3] Yaghi O M, Li H, Davis C, et al. Acc. Chem. Rev., 1998,31: 474-484
4. [4]
  [4] Janiak C. Angew. Chem., Int. Ed. Engl., 1997,36:1431-1434
5. [5]
  [5] Goodgame D M L, Grachvogel D A, Williams D J. Angew. Chem., Int. Ed. Engl., 1999,38:153-156
6. [6]
  [6] MacDonald J W, Whitesides G M. Chem. Rev., 1994,94:2383-2420
7. [7]
  [7] Eddaoudi M, Kim J, O'Keeffe M, et al. J Am. Chem. Soc., 2002,124:376-377
8. [8]
  [8] Tabellion F M, Seidel S R, Arif A M, et al. Angew. Chem., Int. Ed., 2001,40:1529
9. [9]
  [9] Pan L, Woodlock E B, Wang X, et al. Chem. Commun., 2001, 35:1762-1763
10. [10]
  [10] Tong M L, Wu Y M, Ru J, et al. Inorg. Chem., 2002,41:4846-4848
11. [11]
  [11] Sheldrick G M. SHELXL-97, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1997.
12. [12]
  [12] Sheldrick G M. SHELXL-97, Program for Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
13. [13]
  [13] Zhao W W, Zhong X G, Zhang Y L, et al. Polymer, 1994,35 (15):3348-3350
14. [14]
  [14] Huang Y G, Zhou Y F, Wu B L, et al. Chinese J. Struct. Chem., 2005,24:1123-1128
15. [15]
  [15] Xue X, Wang X S, Wang L Z, et al. Inorg. Chem., 2002,41: 6544-6546
16. [16]
  [16] Tao J, Tong M L, Shi J X, et al. Chem. Commun., 2002,42: 2043-2044
17. [17]
  [17] Tao J, Shi J X, Tong M L. Inorg. Chem., 2001,40:6328-6330
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沈阳化工大学材料科学与工程学院沈阳 110142