Citation: JIANG Jing, REN Shi-Bin, LIN Yong-Qiang, WU Tao, ZHANG Xiao-Peng, HAN De-Man, LIANG Hua-Ding, LI Fang, JIA Wen-Ping. Synthesis of Chiral Metal-Organic Framework and Study of Its Properties Based on Tetrakis(3-pyridyloxymethylene)methane and Helical CuCN Chains[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1539-1544. doi: 10.3969/j.issn.1001-4861.2013.00.257 shu

Synthesis of Chiral Metal-Organic Framework and Study of Its Properties Based on Tetrakis(3-pyridyloxymethylene)methane and Helical CuCN Chains

1.
1 School of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou, Zhejiang 17000, China;

Received Date: 6 March 2013
Available Online: 20 April 2013
Fund Project: 浙江省自然科学基金(No.LY12B01006) (No.LY12B01006)浙江省科技计划项目(No.2012C₃7028,2011C₃7055) (No.2012C₃7028,2011C₃7055)台州市科技局项目(No.102XCP08) (No.102XCP08)

A novel homochiral metal-organic framework is successfully constructed by an achiral ligand and 1D helical CuCN chains: [Cu₄(CN)₄(L)₂]_n (L=tetrakis(3-pyridyloxymethylene)methane) (1); the helixes assembled by copper(Ⅰ) and CN groups in situ generated are left-handed and transform the framework to chiral. This is the first example of chiral MOFs induced by flexible conformation of semigrid tetrahedral ligand. In addition, the chiral property of bulk products is confirmed by VCD spectra, the thermal stability and dielectric properties are also investigated. CCDC: 921046.
- chiral metal-organic framework;semigrid tetrahedral ligand;helical CuCN chains;dielectric properties
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