Citation: LI Qing-Xiang, XIANG Ai-Hua, MENG Xiang-Gao. Synthesis, Characterization, Electrochemical Property and DNA Binding Property of Nickel(Ⅱ) Complex with 1,4,7-Tris-(benzimidazole-2-yl-methyl)-1,4,7-triazacyclononane[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1428-1432. doi: 10.3969/j.issn.1001-4861.2013.00.243 shu

Synthesis, Characterization, Electrochemical Property and DNA Binding Property of Nickel(Ⅱ) Complex with 1,4,7-Tris-(benzimidazole-2-yl-methyl)-1,4,7-triazacyclononane

1.
1 Key Laboratory for Green Chemical Process of Ministry of Education and Hubei Key Laboratory of Novel Chemical Reactor and Green Chemical Technology, Wuhan Institute of Technology, Wuhan 430073, China;

Received Date: 12 September 2012
Available Online: 28 February 2013
Fund Project: 国家自然科学基金(No.20571058) (No.20571058)湖北省教育厅科学技术研究项目(No.D20111501)资助项目。 (No.D20111501)

A new nickel(Ⅱ) complex: [Ni(tribentacn)](ClO₄)₂, (tribentacn=1,4,7-tris-(benzimidazole-2-yl-methyl)-1,4,7-triazacyclononane), has been synthesized and characterized by elemental analysis and IR spectra. The crystal structure of this complex was determined by X-ray diffraction analysis, crystallized in the triclinic system, space group P1, Z=2, a=1.208 01(8) nm, b=1.217 66(8) nm, c=1.281 42(8) nm, α=78.809(3)°, β=77.094(2)°, γ=66.460(3)°, R₁=0.078 0. The nickel(Ⅱ) atom is octahedrally coordinated by six nitrogen atoms of three benzimidazoles and 1,4,7-triazacyclononane (tacn). The electrochemical property and interactions with pBR322 DNA of the complex were studied. CCDC: 841482.
- triazacyclononane;benzimidazol-2-ylmethyl;nickel(Ⅱ) complex;crystal structure;DNA;electrochemical property
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沈阳化工大学材料科学与工程学院沈阳 110142