Citation: CHEN Xiao-Hua, WU Qiong-Jie, LU Wei, YANG Ming-Xing, CHEN Li-Juan. Syntheses and Crystal Structures of Two Vanadium Complexes with Salicyloylhydrazone Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1521-1526. doi: 10.3969/j.issn.1001-4861.2013.00.235 shu

Syntheses and Crystal Structures of Two Vanadium Complexes with Salicyloylhydrazone Ligands

1.
1 College of Materials Science and Engineering, Fujian Normal University, Fuzhou 350007, China;

Received Date: 4 September 2012
Available Online: 24 February 2013
Fund Project: 福建省教育厅课题(No.JB10007)资助项目。 (No.JB10007)

Two new V(V) complexes, [VOL¹(C₂H₅O)]₂(1) (H₂L¹=2-hydroxyacetophenone salicyloylhydrazone) and [VOL²(i-C₃H₇O)](2) (H₂L²=salicylaldehyde salicyloylhydrazone) have been synthesized and characterized by elemental analysis, IR, UV and X-Ray diffraction. Complex 1 reveals a centrosymmetric dimer, in which the two vanadium centers are bridged by phenolic oxygen atoms. Each vanadium(V) in 1 exhibits a slightly distorted octahedral geometry. While complex 2 is a mononuclear structure, in which vanadium(V) has a distorted square-pyramidal geometry. Complex 2 forms an infinite 1D chain-like supramolecular structure by intermolecular hydrogen bonds. The electrochemical property for complex 2 was studied with an electrochemical analyzer. CCDC: 889674, 1; 889675, 2.
- hydrazone;vanadium(V) complex;crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142