Citation: LU Wen-Guan, LIU Hong-Wen, YIN Xu-Guang, LAN Lu-Mei, LIU Ke-Mei, LIU Hai-Yao, HUANG Jing, WU Qi-Xin, LIAO Cai-Lan. Synthesis, Structure and Fluorescent Properties of Two Zn(Ⅱ) Coordination Polymers with 4-Connected Coordination Network[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1433-1441. doi: 10.3969/j.issn.1001-4861.2013.00.234 shu

Synthesis, Structure and Fluorescent Properties of Two Zn(Ⅱ) Coordination Polymers with 4-Connected Coordination Network

1.
Department of Chemistry, Shaoguan University, Shaoguan, Guangdong 512005, China

Received Date: 27 January 2013
Available Online: 26 March 2013
Fund Project: 国家自然科学基金(No.21071099) (No.21071099)

Reactions of 5-amino-tetrazole (HATz) and 4-pyridinecarboxylic acid (HPyc) with ZnSO₄·7H₂O or Zn(NO₃)₂·6H₂O under N,N'-dimethylformamide (DMF) solvothermal condition, yielded two new Zn(Ⅱ) coordination polymers of {[(CH₃)2NH₂]·[Zn(ATz)(SO₄)]}_n (1) and {[Zn(ATz)(Pyc)]·0.5DMF}_n (2), respectively, which have been structurally characterized by elemental analysis, infrared spectroscopy, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray diffraction. The results of structural analysis reveal that complex 1 possesses an 2D undulated layer structure, in which 2D anion (4,4) layer of [Zn(ATz)(SO₄)]_nⁿ-and [(CH₃)2NH₂]⁺ cations are assembled together via strong hydrogen bonding interactions. A remarkable feature of complex 2 is a two-fold interpenetrating 3D microporous metal-organic framework with 4-connected diamondoid topology, in which free DMF molecules locate in the channels. Luminescent properties studies indicate that complexes 1 and 2 exhibit intense fluorescent emissions at λ_max=445 nm and 458 nm when excited at 350 nm, respectively, in the solid state at room temperature. CCDC: 921342, 1; 921343, 2.
- coordination polymer;5-amino-tetrazole;mixed-ligand;crystal structure;fluorescence
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沈阳化工大学材料科学与工程学院沈阳 110142