Citation: LIN Zi-Xia, WANG Gang, ZHENG Ming-Bo, ZHAO Bin, LI Nian-Wu, PU Lin, SHI Yi. Ultra-Long-Term Cyclability of Li₄Ti₅O₁₂/Graphene Nanocomposite Anode Material with Three-Dimensional Continuous Structure for Lithium-Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1465-1470. doi: 10.3969/j.issn.1001-4861.2013.00.232 shu

Ultra-Long-Term Cyclability of Li₄Ti₅O₁₂/Graphene Nanocomposite Anode Material with Three-Dimensional Continuous Structure for Lithium-Ion Batteries

1.
Nanjing National Laboratory of Microstructures, School of Electronic Science and Engineering, Nanjing University, Nanjing 210093, China

Received Date: 28 January 2013
Available Online: 10 April 2013
Fund Project: 国家重点基础研究发展计划(No.2013CB932900,2011CB922100) (No.2013CB932900,2011CB922100)国家自然科学基金(No.51202106,60990314,61106089) (No.51202106,60990314,61106089)江苏省自然科学基金(No.KB2011011)资助项目。 (No.KB2011011)

Li₄Ti₅O₁₂/graphene nanocomposite was synthesized using thermally exfoliated graphene with a three-dimensional continuous nanoporous structure as the matrix. The precursors were introduced into the interior nanopores of thermally exfoliated graphene by the ethanol evaporation method. After heat treatment, Li₄Ti₅O₁₂ nanoparticles were formed in situ in the nanopores of thermally exfoliated graphene. As an anode material for lithium-ion batteries, the three-dimensional continuous structure of thermally exfoliated graphene ensures sufficient contact between Li₄Ti₅O₁₂ and graphene during the long cycling. Consequently, the nanocomposite shows superior cyclic stability. The capacity retention is still as high as 94% after 5 000 cycles at 5C.
- Li₄Ti₅O₁₂;graphene;nanocomposite;anode;lithium-ion battery
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沈阳化工大学材料科学与工程学院沈阳 110142

Ultra-Long-Term Cyclability of Li4Ti5O12/Graphene Nanocomposite Anode Material with Three-Dimensional Continuous Structure for Lithium-Ion Batteries

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通讯作者: 陈斌, bchen63@163.com

Ultra-Long-Term Cyclability of Li₄Ti₅O₁₂/Graphene Nanocomposite Anode Material with Three-Dimensional Continuous Structure for Lithium-Ion Batteries