Citation: PAN Ming-Chu, WANG Yan-Nan, XU Hai-Quan, YANG Yu-Xiang, LIU Xiang-Nong. Preparation and Characterization of Black Titanium Oxides with Large Surface Area[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1345-1354. doi: 10.3969/j.issn.1001-4861.2013.00.226 shu

Preparation and Characterization of Black Titanium Oxides with Large Surface Area

1.
1 College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, Zhejiang 325035, China;

Received Date: 14 December 2012
Available Online: 27 March 2013
Fund Project: 温州市科技计划项目(G20100173) (G20100173) 国家自然科学基金(29201004)资助项目。 (29201004)

In this paper, the precursor hydrazine titanium succinic acid was first prepared by pH value controlled precipitation method, after that, the titanium black pigment, namely, black titanium suboxides with large surface area were prepared by thermal decomposing the precursor. The black titanium suboxides were characterized by Brunauer-Emmett-Teller (BET) surface area, Energy dispersive x-ray spectrometry (EDS), X-ray Photoelectron Spectroscopy(XPS),X-ray diffraction patterns (XRD), high resolution scanning electron microscopy (HRSEM), nitrogen sorption analysis, laser particle size analyzer, and color i5 colorimeter spectrophotometer. The composition of black titanium suboxides was determined as 2TiO₂·Ti₂O₃, and its surface area is 53.854 4 m²·g^-1. The influences of acid source, the amount of hydrazine hydrate, acid/TiCl₃ ratio, reaction time, pH, NaOH concentration, the calcination temperature and various reaction parameters on the particle size, the distribution uniformity and blackness of black titanium suboxides were discussed. The composition of the precursor with its molecular formula as [Ti(C₄H₄O₄)₂]_0.85·2Ti₂O₃·6N₂H₄·3H₂O was analyzed by Elemental analyzer and plasma spectrometer. From these data, the formation mechanism of the black titanium suboxides was deduced. These provide an important basis for the preparation of novel mixed-valence material black titanium suboxides.
- titanium oxide;coprecipitation;succinic acid hydrazine hydrate titanates;thermal decomposition
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沈阳化工大学材料科学与工程学院沈阳 110142