Citation: HUANG Yan-Ju, NI Liang, TONG Bo, XING Wei-Nan. Hydrothermal Synthesis and Crystal Structure of a Cobalt Coordination Compound with Quinoxaline-Type Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1289-1294. doi: 10.3969/j.issn.1001-4861.2013.00.221 shu

Hydrothermal Synthesis and Crystal Structure of a Cobalt Coordination Compound with Quinoxaline-Type Ligand

1.
1. Department of Chemistry, Tonghua Normal University, Tonghua, Jilin 134002, China;

Received Date: 21 July 2012
Available Online: 4 March 2013

One compound [Co(AIP)(HAIP)₂]·(OH)₂(LH=2-(9-anthryl)-1H-imidazo[4,5-f][1,10] phenanthroline) 1 has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, TG and single-crystal X-ray diffraction. The compound 1 crystallizes in the monoclinic system, space group C2/c, with a=1.152 9(2), b=3.673 6(7), c=1.584 1(3) nm, β=107.73(3), V=6.382(2) nm³, Z=4 (at 291(2) K). In the crystal structure, the Co(Ⅲ) ion is six match coordination with six nitrogen atoms which from two different HAIP ligands and one AIP ligand, assuming a slightly distorted octahedral.
- crystal structure;hydrothermal synthesis;cobalt compound
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沈阳化工大学材料科学与工程学院沈阳 110142