Citation: ZHENG Jia-Fei, ZHENG Ming-Bo, LI Nian-Wu, LU Hong-Ling, QIU Lan, CAO Jie-Ming, JI Guang-Bin. Preparation of Graphene Coated Carbon Nanotube-Sulfur Composite and Its Performance for Lithium-Sulfur Battery[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1355-1360. doi: 10.3969/j.issn.1001-4861.2013.00.218 shu

Preparation of Graphene Coated Carbon Nanotube-Sulfur Composite and Its Performance for Lithium-Sulfur Battery

1.
1 Nanomaterials Research Institute, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China;

Received Date: 10 January 2013
Available Online: 15 March 2013
Fund Project: 国家自然科学基金(No.51202106,No.51172109) (No.51202106,No.51172109)江苏省自然科学基金(No.BK2010497)资助项目。 (No.BK2010497)

To solve the main problems encountered in the lithium-sulfur battery research and practical application, a simple and effective hydrothermal reduction of graphene oxide was employed to encapsulate commercial carbon nanotube-sulfur (CNT-S) nanocomposite in this study, then an effective type of graphene coated CNT-S nanostructure was formed. The polysulphide anions diffusion phenomenon was effectively restrained by the graphene coating structure. The nanocomposites were characterized by X-ray diffraction and scanning electron microscope. The results indicated that elemental sulfur was uniformly distributed across the CNT, and a layer of graphene coated on the surface of CNT-S nanocomposite. The electrochemical test results showed that the graphene coating nanostructure obviously improved the lithium-sulfur battery performance of the CNT-S nanocomposite.
- graphene;lithium-sulfur battery;carbon nanotube;sulfur
1. [1]
  [1] Yang Y, Yu G H, Cui Y, et al. ACS Nano, 2011,5(11):9187-9193
2. [2]
  [2] Bruce P G, Freunberger S A, Hardwick L J, et al. Nat. Mater., 2012,11:19-29
3. [3]
  [3] Bruce P G, Hardwick L J, Abraham K M. MRS Bull., 2011, 36(7):506-512
4. [4]
  [4] Jayaprakash N, Shen J, Moganty S S, et al. Angew. Chem., 2011,123(26):6026-6030
5. [5]
  [5] Wang C, Chen J J, Zheng M S, et al. Electrochimica Acta, 2010,55(23):7010-7015
6. [6]
  [6] Ji X L, Evers S, Nazar L F, et al. Nat. Commun., 2011,2:325
7. [7]
  [7] Ji X L, Lee K T, Nazar L F. Nat. Mater., 2009,8:500-506
8. [8]
  [8] Xiao L F, Cao Y L, Liu J, et al. Adv. Mater., 2012,24(9): 1176-1181
9. [9]
  [9] Ji X L, Nazar L F. J. Mater. Chem., 2010,20:9821-9826
10. [10]
  [10] DONG Quan-Feng(董全峰), WANG Chong(王翀), ZHENG Ming-Sen(郑明森). Prog. Chem.(Huaxue Jinzhan), 2011,23 (2/3):533-539
11. [11]
  [11] YANG Xue-Bing(杨学兵), WANG Chuan-Xin(王传新), WANG Jian-Hua(汪建华), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2011,27(12):2431-2436
12. [12]
  [12] Cao Y L, Li X L, Liu J, et al. Phys. Chem. Chem. Phys., 2011,13:7660-7665
13. [13]
  [13] Wang J Z, Lu L, Xu X, et al. J. Power Sources, 2011,196 (16):7030-7034
14. [14]
  [14] Liang C D, Dudney N J, Howe J Y. Chem. Mater., 2009,21 (19):4724-4730
15. [15]
  [15] Wang J, Chew S Y, Zhao Z W, et al. Carbon, 2008,46(2): 229-235
16. [16]
  [16] Yuan L X, Yuan H P, Qiu X P, et al. J. Power Sources, 2009,189(2):1141-1146
17. [17]
  [17] WU Feng(吴峰), WU Sheng-Xian(吴生先), CHEN Ren-Jie (陈人杰), et al. New Carbon Mater.(Xinxing Tancailiao), 2010,25(6):421-425
18. [18]
  [18] Dörfler S, Hagen M, Althues H, et al. Chem. Commun., 2012,48:4097-4099
19. [19]
  [19] XUE Lu-Ping(薛露平), ZHENG Ming-Bo(郑明波), SHEN Cheng-Fei(沈辰飞), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(8):1375-1381
20. [20]
  [20] Zhang F F, Zhang X B, Wang L M, et al. J. Mater. Chem., 2012,22:11452-11454
21. [21]
  [21] Wang H L, Yang Y, Dai H J, et al. Nano Lett., 2011,11(7): 2644-2647
22. [22]
  [22] Li N W, Zheng M B, Cao J M, et al. Chem. Commun., 2012, 48(34):4106-4108
23. [23]
  [23] Zhou Y, Bao Q L, Zhong Y L, et al. Chem. Mater., 2009,21 (13):2950-2956
24. [24]
  [24] Shen J F, Yan B, Shi M, et al. J. Mater. Chem., 2011,21: 3415-3421
25. [25]
  [25] Navarro C B, Coronado E, Gastaldo C M, et al. Nanoscale, 2012,4:3977-3982
26. [26]
  [26] Hummers W S, Offeman R E. J. Am. Chem. Soc., 1958,80 (6):1339-1339
27. [27]
  [27] ZHUO Hua-Lan(卓华兰), YUAN Zhong-Zhi(袁中直), LIU Jin-Cheng(刘金城). Chinese J. Power Sources(Dianyuan Jishu), 2010,34(12):1242-1245
1. [1]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
2. [2]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
3. [3]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
4. [4]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
5. [5]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100015-. doi: 10.3866/PKU.WHXB202310024
6. [6]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
7. [7]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
8. [8]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
9. [9]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
10. [10]
  Hongyao Li , Youyan Liu , Luwei Dai , Min Yang , Qihui Wang . The Blessing of Indium Sulfide：Confronting the Narrow Path with Uric Acid. University Chemistry, 2024, 39(5): 325-335. doi: 10.3866/PKU.DXHX202311104
11. [11]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
12. [12]
  Yu ZHANG , Fangfang ZHAO , Cong PAN , Peng WANG , Liangming WEI . Application of double-side modified separator with hollow carbon material in high-performance Li-S battery. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1218-1232. doi: 10.11862/CJIC.20230412
13. [13]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
14. [14]
  Yiming Liang , Ziyan Pan , Kin Shing Chan . One Drink, Two Tears in the Central Nervous System: The Perils of Disulfiram-Like Reactions. University Chemistry, 2025, 40(4): 322-325. doi: 10.12461/PKU.DXHX202406016
15. [15]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
16. [16]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
17. [17]
  Hong CAI , Jiewen WU , Jingyun LI , Lixian CHEN , Siqi XIAO , Dan LI . Synthesis of a zinc-cobalt bimetallic adenine metal-organic framework for the recognition of sulfur-containing amino acids. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 114-122. doi: 10.11862/CJIC.20240382
18. [18]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
19. [19]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
20. [20]
  Tianqi Bai , Kun Huang , Fachen Liu , Ruochen Shi , Wencai Ren , Songfeng Pei , Peng Gao , Zhongfan Liu . 石墨烯厚膜热扩散系数与微观结构的关系. Acta Physico-Chimica Sinica, 2025, 41(3): 2404024-. doi: 10.3866/PKU.WHXB202404024

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(709)
HTML views(141)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142