Citation: BAO Jin-Ting, CHENG Mei-Ling, LIU Qi, HAN Wei, JI Yun-Zhou, ZHAI Chang-Wei, HONG Jian, SUN Xiao-Qiang. Cobalt and Nickel Supramolecular Complexes with Hexagonal Channels Constructed from 5-Methyl-1H-Pyrazole-3-Carboxylic Acid：Synthesis, Crystal Structures and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1504-1512. doi: 10.3969/j.issn.1001-4861.2013.00.215 shu

Cobalt and Nickel Supramolecular Complexes with Hexagonal Channels Constructed from 5-Methyl-1H-Pyrazole-3-Carboxylic Acid：Synthesis, Crystal Structures and Properties

1.
1 School of Petrochemical Engineering and Jiangsu Province Key Laboratory of Fine Petro-chemical Technology, Changzhou University, Changzhou, Jiangsu 213164, China;

Received Date: 26 November 2012
Available Online: 25 February 2013
Fund Project:

The new monomeric complexes of [M(MPA)₂(H₂O)₂] (1: M=Co; 2: M=Ni) (HMPA=5-methyl-1H-pyrazole-3-carboxylic acid) were synthesized by the reaction of 5-methyl-1H-pyrazole-3-carboxylic acid with CoCl₂·6H₂O and Ni(NO₃)₂·6H₂O, respectively. The compounds were characterized by elemental analysis, IR spectra, single crystal X-ray diffraction. The structural parameters of 1 and 2 were analyzed as follows: 1, Hexagonal, R3c, a=1.48394(4) nm, b=1.483 94(4) nm, c=3.207 66(6) nm, V=6.1172(3) nm³, Z=18; 2, Hexagonal, R3c, a=1.466 53(14) nm, b= 1.466 53(14) nm, c=3.243 0(6) nm, V=6.040 3(14) nm³, Z=18. Metal ions have all octahedral geometry coordinated by two nitrogen atoms and two oxygen atoms from two MPA-ligands, two oxygen atoms from two H₂O molecules. In both complexes, the independent components [M(MPA)₂(H₂O)₂] are connected by intermolecular hydrogen bonds to form a three-dimensional architecture with hexagonal channels. Thermogravimetric analyses show that 1 and 2 have higher thermal stability. In addition, the luminescent properties and electrochemical properties of complexes 1 and 2 have also been investigated. CCDC: 900677, 1; 900678, 2.
- cobalt(Ⅱ);nickel(Ⅱ);5-methyl-1H-pyrazole-3-carboxylic acid;crystal structure;luminescent property;electrochemical property
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