Citation: XIE Feng-Xia, ZHANG Xin-Xin, ZHANG Dan, HUA Min, ZHANG Feng-Xing. Synthesis, Structure and Properties of Sm(Ⅲ) and Dy(Ⅲ) Complexes with Pyridine-2,5-dicarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1497-1503. doi: 10.3969/j.issn.1001-4861.2013.00.214 shu

Synthesis, Structure and Properties of Sm(Ⅲ) and Dy(Ⅲ) Complexes with Pyridine-2,5-dicarboxylic Acid

1.
1 College of Environment and Chemical Engineer, Xi'an Polytechnic Univercity, Xi'an 710048, China;

Received Date: 22 May 2012
Available Online: 6 March 2013
Fund Project: 西安工程大学校科研启动基金(No.BS0902)资助项目。 (No.BS0902)

Two new Lanthanide complexes [Ln(pydc)₂(H₂O)₅]·4H₂O (Ln=Sm (1), Dy (2)) were obtained by the hydrothennal reactions of Ln(NO₃)₃·6H₂O, pyridine-2,5-dicarboxylic acid (H₂pydc) with 1:1 mole ratio. Single-crystal X-ray diffraction analysis reveals that both the crystals belong to monoclinic,space group C2/c. The structure and property of complexes have been characterized by elemental analysis, thermal analyses, IR spectra and Fluorescence. The single crystal structures show that the two complexes are isomorphic and have zero-dimensional structures and hydrogen bonds result in three-dimensional supramolecular structures. the coordination number of central ion Ln(Ⅲ) is nine. The complex 1 and 2 exhibit intense luminescence in the liquid state at room temperature. CCDC: 869044, 1; 874032, 2.
- lanthanide;coordination complex;carboxylic acid;thermalsynthesis;fluorescence
1. [1]
  [1] Ma H Y, Spaniol T P, Okuda J. Dalton Trans., 2003:4770-4780
2. [2]
  [2] Thibon A, Pierre V C. J. Am. Chem. Soc., 2009,131:434-435
3. [3]
  [3] Shen Z Q, Ouyang J. Handbook on the Physics and Chemistry of Rare Earths. North Holand: Elsevier Science Publisher, 1987:61
4. [4]
  [4] Jia J H, Lin X, Blake A J, et al. Inorg. Chem., 2006,45:8838-8840
5. [5]
  [5] ZHANG Xing-Jing (张兴晶), XING Yong-Heng (邢永恒), WANG Chun-Guang (王春光), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2009,25:407-411
6. [6]
  [6] Chen B L, Yang Y, Zapata F, et al. Adv. Mater., 2007,19: 1693-1696
7. [7]
  [7] FENG Lin(冯林), JIANG Chong-Qiu(江崇球), SHI Jing-Min (石敬民). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2007,23(9):1635-1638
8. [8]
  [8] YANG Rui(杨锐), HE Shui-Yang(何水样), WU Wang-Ting (武望婷), et al. Chem. J. Chinese Universities(Gaodeng Xuexiao Huaxue Xuebao), 2005,26(3):401-406
9. [9]
  [9] GUO Dong-Cai(郭栋才), SU Wan-Liang(舒万良), ZHOU Yue(周悦), et al. Chinese Rare Earths(Xitu), 2004,25(2):4-6
10. [10]
  [10] ZHOU Xia-Ying(周夏英), HUANG Yong-Qing(黄永清), SUN Wei-Yin(孙为银). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2008,24(11):1733-1737
11. [11]
  [11] JIANG Zu-Cheng(江祖成), CAI Ru-Xiu(蔡汝秀), ZHANG Hua-Shan(张华山). REE Analysis Chemistry. 2nd Ed.(稀土元素分析化学.2版). Beijing: Science Press, 2001:2-25
12. [12]
  [12] Wang C G, Xing Y H, Li Z P, et al. J. Mol. Struct., 2009, 921:126-131
13. [13]
  [13] Huang Y G, Jiang F L, Yuan D Q, et al. Cryst. Growth Des., 2008,8:166-168
14. [14]
  [14] Bruker 2000, SMART (Version 5.0), SAINT-plus(Version 6), SHELXTL (Version 6.1)
15. [15]
  [15] Liu Q Y, Xu L. Eur. J. Inorg. Chem., 2005:3458-3466
16. [16]
  [16] Pan L, Huang X Y, et al. Angew. Chem., Int. Ed., 2000,39: 527-529
17. [17]
  [17] Malek J. Thermochim. Acta, 1989,138(1/2): 337-369
18. [18]
  [18] HU Rong-Zu(胡荣祖), SHI Qi-Zhen(史启祯). Thermal Analysis Kinetics(热分析动力学). Beijing: Science and Technology Press, 2001:1-20
19. [19]
  [19] Matthias Wagner, Translated by LU Li-Ming(陆立明). Thermal Analysis in Practice(热分析应用基础). Shanghai: Donghua University Press, 2011:114-124
20. [20]
  [20] XU Jin-Gou(许金钩), WANG Zun-Ben(王尊本). Fluoresce-nce Analysis Method. 3rd Ed.(荧光分析法.3版). Beijing: Science Press, 2006:131-150
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