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Citation: CHU Zhao-Hua, CHEN Yan-Min, XIE Qing-Fan. Syntheses, Crystal Structures and Magnetic Properties of Two 3d-4f Heterometallic Complexes [Fe(phen)3]2[FeLn(H2O)(tiron)3]·6H2O (Ln=HoⅢ, YbⅢ)[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1385-1390. doi: 10.3969/j.issn.1001-4861.2013.00.213 shu

Syntheses, Crystal Structures and Magnetic Properties of Two 3d-4f Heterometallic Complexes [Fe(phen)3]2[FeLn(H2O)(tiron)3]·6H2O (Ln=HoⅢ, YbⅢ)

  • 1.

    1 Department of Chemistry, HanShan Normal University, Chaozhou, Guangdong 521041, China;

  • Received Date: 1 July 2012
    Available Online: 2 February 2013

    Fund Project: 广东省科技厅科技项目(No.2011B090400521) (No.2011B090400521)福建省科技厅科技项目(No.2008F5053)资助项目。 (No.2008F5053)

  • Two isostructural heteronuclear complexes [Fe(phen)3]2[FeLn(H2O)(tiron)3]·6H2O (Ln=Ho (1) and Yb (2)), Na2H2tiron=disodium 4,5-dihydro-xybenzene-1,3-disulfonate) were self-assembly synthesized via hydrothermal reaction. The complexes crystallized in the cubic system, space group P213. In [FeLn(H2O)(tiron)3]6-unit was revealed that the Fe3+ ion is in a FeO6 distorted trigonal anti-prism coordination polyhedron completed by six phenolate O atoms from three tiron4-ligands, and Ln3+ in a LnO7 distorted monocapped trigonal anti-prism coordination polyhedron completed by three phenolate μ2-O atoms and three O atoms from sulfonate groups of three ligands and one O atom from coordinated water. The [Fe(phen)3]3+ cations and [FeCe(tiron)3]6-anions via π-π interaction between phen ligands and electric attraction between cations and anions was assembled into multi-dimensional supramolecule. The magnetic properties of the complexes were been determined in the temperature range 2~300 K, indicating that the antiferromagnetic interaction between the central Ln(Ⅲ)-Fe(Ⅲ) ions. CCDC: 866880, 1; 867589, 2.
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