Citation: ZENG Xiao-Zhe, ZHANG Ai-Yun, HE Chong, LI Yan-Wei. Synthesis, Structure and Thermal Properties of Two Cerium(Ⅳ) Complexes with 2,6-Pyridinedicarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1557-1562. doi: 10.3969/j.issn.1001-4861.2013.00.211 shu

Synthesis, Structure and Thermal Properties of Two Cerium(Ⅳ) Complexes with 2,6-Pyridinedicarboxylic Acid

1.
Department of Physical and Chemistry, Henan Polytechnic University, Jiaozuo, Henan 454000, China

Received Date: 29 March 2012
Available Online: 7 March 2013
Fund Project: 河南省高等院校自然科学研究项目(No.2009A150011)资助项目。 (No.2009A150011)

Two cerium(Ⅳ) complexes [Ce(dipic)₃]·(H₂bipy)·4H₂O (1) and [Ce(dipic)₃]·(H₂bpa)·3.5H₂O (2) (2,6-H₂dipic=2,6-pyridinedicarboxylic acid, bipy=4,4'-bipyridine, bpa=Bis(4-pyridyl)amine) have been hydrothermally synthesized and structurally characterized via elemental analysis, IR spectra, TG and single-crystal X-ray diffraction. Both complexes crystallize in triclinic, space group P1 with a=1.014 32(11) nm, b=1.253 64(13) nm, c=1.448 89(14) nm, V=1.662 77(6) nm³, Z=2, R₁=0.064 1, wR₂=0.149 4 for 1, and a=1.039 30(5) nm, b=1.604 02(8) nm, c=2.021 65(10) nm, V=3.304 5(3) nm³, Z=2, R₁=0.039 8 and wR₂=0.104 9 for 2. The central metal Ce(Ⅳ) ions of both complexes are surrounded by three wholly unprotonated dipicolinate groups in the usual tridentate mode. Thermogravimetric analysis shows that the two complexes are stable up to 64 and 50℃, respectively. CCDC: 856834, 1; 856608, 2.
- 2,6-pyridinedicarboxylic acid;cerium(Ⅳ) complex;crystal structure;thermal property
1. [1]
  [1] Piguet C, Bünzil J C, Bernardinelli G. J. Am. Chem. Soc, 1996,118:6681-6697
2. [2]
  [2] Li B, Gu W, Zhang L Z, et al. Inorg. Chem., 2006,45:10425-10427
3. [3]
  [3] Darren B, Timothy J P, Edmund J C. J. Am. Chem. Soc., 2004,126:6106-6114
4. [4]
  [4] CHEN Zhi-Min(陈志敏), LI Dong-Ping(李东平), LI Hui-Quan(李慧泉). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2008,24:1907-1911
5. [5]
  [5] Wang N, Yue S T, Liu Y L, et al. Cryst. Growth Des., 2009, 9:368-371
6. [6]
  [6] Shi F N, Silva L C, Trindade T, et al. Cryst. Growth Des., 2009,9:2098-2109
7. [7]
  [7] Yang P, Wu J Z, Yu Y. Inorg. Chim. Acta, 2009,362:1907-1912
8. [8]
  [8] Li X H, Shi Q, Hu M L, et al. Inorg. Chem. Commun., 2004, 7:912-914
9. [9]
  [9] Song H H, Li Y J. Inorg. Chim. Acta, 2008,361:1421-1425
10. [10]
  [10] Luo J H, Hong M C, Wang R H, et al. Inorg. Chem., 2003, 42:4486-4488
11. [11]
  [11] Wang Z, Bai F Y, Xing Y H, et al. Inorg. Chim. Acta, 2010, 363:669-675
12. [12]
  [12] Liu M S, Yu Q Y, Cai Y P, et al. Cryst. Growth Des., 2008, 8:4083-4091
13. [13]
  [13] Prasad T K, Sailaja S, Rajasekharan M V. Polyhedron, 2005,24:1487-1496
14. [14]
  [14] Chantal B C, Jeannette D G, Auguste F, et al. Inorg. Chim. Acta, 2008,361:2909-2917
15. [15]
  [15] HUANG Yan-Ju(黄艳菊), CUI Yun-Cheng(崔运成), DU Gang(杜刚). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2009,25:1882-1884
16. [16]
  [16] HUANG Yan-Ju(黄艳菊), NI Liang(倪良), WANG Lei(王蕾), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27:157-161
17. [17]
  [17] CHEN Zi-Yun(陈梓云), PENG Meng-Xia(彭梦侠). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2007,23:2093-2096
18. [18]
  [18] Bo Q B, Sun G X, Geng D L. Inorg. Chem., 2010,49:561-571
19. [19]
  [19] Stephen M S, Ronald M S, Robert L L. Inorg. Chim. Acta, 2008,361:317-326
20. [20]
  [20] Sheldrick G M. SHELX-97, Program for the Solution and the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
21. [21]
  [21] Swarnabala G, Rajasekharan M V. Inorg. Chem., 1998,37: 1483-1485
22. [22]
  [22] Sailaja S, Rajasekharan M V. Acta Cryst. E, 2001,57:341-343
23. [23]
  [23] Paula C R, Silva L C, Filipe A P, et al. Inorg. Chem., 2010,49:3428-3440
24. [24]
  [24] Prasad T K, Rajasekharan M V. Cryst. Growth Des., 2006,6: 488-491
25. [25]
  [25] LIN Yong(林勇), CHEN Zi-Yun(陈梓云), YU Xiao-Lan(余晓岚), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2006,22:1468-1472
26. [26]
  [26] LI Xia(李夏), LI Wen-Jun(李文君). Chinese J. Spectroscopy and Spectral Analysis(Guangpuxue Yu Guangpu Fenxi), 1999,19:450-452
27. [27]
  [27] FANG Guang-Rong(方光荣), ZHU Yuan-Yuan(祝媛媛), DU Chun-Fang(杜春芳), et al. Chinese J. Molecular Science (Fenzi Kexue Xuebao), 2006,22:368-371
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沈阳化工大学材料科学与工程学院沈阳 110142