Citation: ZENG Xiao-Zhe, ZHANG Ai-Yun, HE Chong, LI Yan-Wei. Synthesis, Structure and Thermal Properties of Two Cerium(Ⅳ) Complexes with 2,6-Pyridinedicarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1557-1562. doi: 10.3969/j.issn.1001-4861.2013.00.211 shu

Synthesis, Structure and Thermal Properties of Two Cerium(Ⅳ) Complexes with 2,6-Pyridinedicarboxylic Acid

1.
Department of Physical and Chemistry, Henan Polytechnic University, Jiaozuo, Henan 454000, China

Received Date: 29 March 2012
Available Online: 7 March 2013
Fund Project: 河南省高等院校自然科学研究项目(No.2009A150011)资助项目。 (No.2009A150011)

Two cerium(Ⅳ) complexes [Ce(dipic)₃]·(H₂bipy)·4H₂O (1) and [Ce(dipic)₃]·(H₂bpa)·3.5H₂O (2) (2,6-H₂dipic=2,6-pyridinedicarboxylic acid, bipy=4,4'-bipyridine, bpa=Bis(4-pyridyl)amine) have been hydrothermally synthesized and structurally characterized via elemental analysis, IR spectra, TG and single-crystal X-ray diffraction. Both complexes crystallize in triclinic, space group P1 with a=1.014 32(11) nm, b=1.253 64(13) nm, c=1.448 89(14) nm, V=1.662 77(6) nm³, Z=2, R₁=0.064 1, wR₂=0.149 4 for 1, and a=1.039 30(5) nm, b=1.604 02(8) nm, c=2.021 65(10) nm, V=3.304 5(3) nm³, Z=2, R₁=0.039 8 and wR₂=0.104 9 for 2. The central metal Ce(Ⅳ) ions of both complexes are surrounded by three wholly unprotonated dipicolinate groups in the usual tridentate mode. Thermogravimetric analysis shows that the two complexes are stable up to 64 and 50℃, respectively. CCDC: 856834, 1; 856608, 2.
- 2,6-pyridinedicarboxylic acid;cerium(Ⅳ) complex;crystal structure;thermal property
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沈阳化工大学材料科学与工程学院沈阳 110142