Citation: LI Fen-Fang, GUO Yan-Qing. A New 1D Ladder-Like Cadmium(Ⅱ) Coordination Polymer Based on 4-(1H-Imidazol-1-yl)benzoate and Chloro Ligands：Crystal Structure and Luminescence[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1527-1532. doi: 10.3969/j.issn.1001-4861.2013.00.209 shu

A New 1D Ladder-Like Cadmium(Ⅱ) Coordination Polymer Based on 4-(1H-Imidazol-1-yl)benzoate and Chloro Ligands：Crystal Structure and Luminescence

1.
College of Chemistry and Chemical Engineering, Jinzhong University, Jinzhong, Shanxi 030600, China

Received Date: 13 July 2012
Available Online: 18 February 2013
Fund Project: 山西省高等学校科技创新课题(No.20121027)资助项目。 (No.20121027)

The self-assembly of 4-(1H-Imidazol-1-yl)benzoic acid and CdCl₂ under hydrothermal condition gave a new 1D cadmium coordination polymer, [Cd(imbz)(Cl)(H₂O)]_n (1) (imbz=4-(1H-Imidazol-1-yl)benzoate), which has been characterized by elemental analysis, IR, TGA and single-crystal X-ray diffraction. The imbz ligands link the Cd(Ⅱ) ions to form an infinite 1D zigzag chain, which the neighboring zigzag chains are further connected into a ladder chain through μ₂-Cl ligands. The photoluminescence and lifetime of complex 1 in the solid state at room temperature have been studied. CCDC: 890931.
- cadmium(Ⅱ) coordination polymer;crystal structure;4-(1H-Imidazol-1-yl)benzoate;luminescent
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