Citation: ZENG Ling. Synthesis and Crystal Structure of Two Complexes of Cadmium, Silver Assembled by 1H-Benzotriazole-1-acetic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1149-1156. doi: 10.3969/j.issn.1001-4861.2013.00.198 shu

Synthesis and Crystal Structure of Two Complexes of Cadmium, Silver Assembled by 1H-Benzotriazole-1-acetic Acid

ZENG Ling

1.
College of Chemistry and Chemical Engineering of Bohai University, Jinzhou, Liaoning 121000, China

Received Date: 24 September 2012
Available Online: 17 February 2013

Two coordination polymers {[Cd(btaa)(phen)(CH₃COO)]·H₂O}_n (1), and {[Ag₂(btaa)(4,4-bpy)₂](NO₃)·2H₂O}_n(2) (Hbtaa=1H-benzotriazole-1-acetic acid, phen=1,10-phenanthroline, 4,4-bpy=4,4-bipyridine) were prepared and characterized by IR spectrum, elemental analysis, TG and single-crystal X-ray analyses. The cadmium ion in complex 1 is linked by btaa ligands into one-dimensional helical chain coordination polymer motif. A ladder type of structure was observed in 2 in which two of the [Ag(4,4'-bpy)]n linear chains are bridged by btaa ligands and paired by Ag…Ag interactions and π-π stacking interactions. Moreover, the luminescent property of complex 1 has been investigated in the solid state. CCDC: 901938, 1; 901939, 2.
- 1H-benzotriazole-1-acetic acid;crystal structures;cadmium complex;silver complex
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沈阳化工大学材料科学与工程学院沈阳 110142