Citation: WANG Li-Zhen, ZHANG Wen-Jing, LIU Yu-Jun, GU Shu-Hua, SUN Xin-Ke. Influence of NaBF₄ on the Graphite Anode for Li-Ion Battery[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1407-1413. doi: 10.3969/j.issn.1001-4861.2013.00.196 shu

Influence of NaBF₄ on the Graphite Anode for Li-Ion Battery

1.
1 Zhengzhou University of Light Industry, Zhengzhou 450001, China;

Received Date: 28 December 2012
Available Online: 11 February 2013

The influence of NaBF₄ on graphite anode for Li-ion battery was studied by adding it into the process of slurry preparation with the methods of galvanostatic charge-discharge, CV, EIS, SEM and EDS. The results showed that: when the amount of NaBF₄ was 2%, not only the reversible capacity at the initial cycle was improved, but also the efficiency. The performances of self-discharge and the cycle stability were all both improved. And its self-discharge rate calculated by capacity was 0.87%·d^-1, reduced15% than it without NaBF₄. The results of CV, EDS and SEM tests both suggested that, NaBF₄ involved in the process of SEI formation, changing its components and morphology.
- Li-ion battery;graphite anode;SEI film;self-discharge;cycle stability
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Influence of NaBF₄ on the Graphite Anode for Li-Ion Battery