Citation: LU Xiao-Jun, ZHOU Fa-Gen, FENG Xing, XUE Sai-Feng, TAO Zhu, ZHU Qian-Jiang. Highly Selective Compounds for Lead and Cadmium：Complexation of α,α’,δ,δ’-Tetramethylcucurbit[6]uril with Transition-Metal and Heavy-Metal Ions[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1513-1520. doi: 10.3969/j.issn.1001-4861.2013.00.192 shu

Highly Selective Compounds for Lead and Cadmium：Complexation of α,α’,δ,δ’-Tetramethylcucurbit[6]uril with Transition-Metal and Heavy-Metal Ions

LU Xiao-Jun ^1,2 ,
ZHOU Fa-Gen ^1,2 ,
FENG Xing ^1,2 ,
XUE Sai-Feng ^1,2 ,
TAO Zhu ^1,2 ,
ZHU Qian-Jiang ^1,2

1.
1 Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guiyang 550025, China;

Received Date: 27 July 2012
Available Online: 25 February 2013
Fund Project: 国家自然科学基金(No.21272045)资助项目。 (No.21272045)

The complexation of α,α',δ,δ'-tetramethylcucurbit[6]uril (TMeQ[6]) complexes with transition-metal ions was studied by differential pulse voltammetry (DPV). The results reveal that this water-soluble cage-type compound shows very high selectivity for Pb²⁺ and Cd²⁺, while it is a masking compound for other transition-metal ions, particularly for Fe³⁺, Co2+, Zn2+, and Cr3+, due to a sharp decrease in the DPV peak current of these metal ions in the presence of TMeQ[6]. Binding constants were determined from voltammetric data. The Pb²⁺ and Cd²⁺ cations display a high binding affinity for TMeQ[6] (K_Pb²⁺=2.12×109 L²·mol^-2, K_Cd²⁺=2.10×10⁹ L²·mol^-2) and form 2:1 n_M²⁺/n_TMeQ[6] complexes. The crystal structure of TMeQ[6]-Pb²⁺ indicates a 2:1 (n_M²⁺/n_TMeQ[6]) complex in the solid state, which is consistent with the results in solution. CCDC: 723280.
- differential pulse voltammetry;TMeQ[6];transition-metal ions;selectivity;complexation
1. [1]
  [1] Freeman W A, Mock W L, Shih N Y. J. Am. Chem. Soc., 1981,103:7367-7368
2. [2]
  [2] Flinn A, Hough G C, Stoddart J F, et al. Angew. Chem. Int. Ed., 1992,31:1475-1477
3. [3]
  [3] Kim J, Jung I S, Kim S Y, et al. J. Am. Chem. Soc., 2000, 122:540-541
4. [4]
  [4] Zhao J Z, Kim H J, Oh J, et al. Angew. Chem. Int. Ed., 2001,40:4233-4235
5. [5]
  [5] Day A I, Blanch R J, Arnold A P, et al. Angew. Chem. Int. Ed., 2002,41:275-277
6. [6]
  [6] Day A I, Arnold A P, Blanch R J, Molecules, 2003,8:74-84
7. [7]
  [7] Isobe H, Sato S, Nakamura E. Org. Lett., 2002,4:1287-1289
8. [8]
  [8] Jon S Y, Selvapalam N, Oh D H, et al. J. Am. Chem. Soc., 2003,125:10186-10187
9. [9]
  [9] Lagona J, Fettinger J C, Isaacs L. Org. Lett., 2003,5:3745-3747
10. [10]
  [10] Sasmal S, Sinha M K, Keinan E. Org. Lett., 2004,6:1225-1228
11. [11]
  [11] Goto K, Oka M, Inazu T. Angew. Chem. Int. Ed., 2004,43: 5019-5022
12. [12]
  [12] Lagona J, Fettinger J C, Isaacs, L. J. Org. Chem., 2005,70: 10381-10392
13. [13]
  [13] Isaacs L, Park S K, Liu S M, et al. J. Am. Chem. Soc., 2005,127:18000-18001
14. [14]
  [14] Huang W H, Liu S M, Zavalij P Y, et al. J. Am. Chem. Soc., 2006,128:14744-14745
15. [15]
  [15] Huang W H, Zavalij P Y, Isaacs L. Angew. Chem. Int. Ed., 2007,46:7425-7427
16. [16]
  [16] Huang W H, Zavalij P Y, Isaacs L. Org. Lett., 2008,10: 2577-2580
17. [17]
  [17] Mock W L. Top. Curr. Chem., 1995,175:1-24
18. [18]
  [18] Lee J W, Samal S, Selvapalam N, et al. Acc. Chem. Res., 2003,36:621-630
19. [19]
  [19] Lagona J, Mukhopadhyay P, Chakrabarti S, et al. Angew. Chem. Int. Ed., 2005,44:4844-4870
20. [20]
  [20] Huang F H, Gibson H W. Prog. Polym. Sci., 2005,30:982-1018
21. [21]
  [21] Kim K, Selvapalam N, Ko Y H, et al. Chem. Soc. Rev., 2007,36:267-279
22. [22]
  [22] Pluth M D, Raymond K N. Chem. Soc. Rev., 2007,36:161-171
23. [23]
  [23] Sindelar V, Silvi S, Parker S E, et al. Adv. Funct. Mater., 2007,17:694-701
24. [24]
  [24] Nau W M, Hennig A, Koner A L. Springer Ser. Fluorescence, 2008,4:185-211
25. [25]
  [25] Buschmann H J, Cleve E, Schollmeyer E. Inorg. Chim. Acta, 1992,193:93-97
26. [26]
  [26] Buschmann H J, Jansen K, Meschke C, et al. Solution Chem., 1998,27:135-140
27. [27]
  [27] Buschmann H J, Cleve E, Jansen K, et al. J. Incl. Phenom. Macro. Chem., 2001,40:117-120
28. [28]
  [28] Buschmann H J, Jansen K, Schollmeyer E. Inorg. Chem. Commun., 2003,6:531-534
29. [29]
  [29] Zhang X X, Krakowiak K E, Xue G P, et al. Ind. Eng. Chem. Res., 2000,39:3516-3520
30. [30]
  [30] Heo J, Kim S Y, Whang D, et al. Angew. Chem. Int. Ed., 1999,38:641-643
31. [31]
  [31] Gerasko O A, Mainicheva E A, Naumova M I, et al. Inorg. Chem., 2008,47:8869-8880
32. [32]
  [32] Gerasko O A, Mainicheva E A, Naumova M I, et al. Eur. J. Inorg. Chem., 2008,3:416-424
33. [33]
  [33] Gerasko O A, Sokolov M N, Fedin V P. Pure App. Chem., 2004,76:1633-1646
34. [34]
  [34] Fedin V P, Siberian D. Russ. J. Coord. Chem., 2004,30:151-158
35. [35]
  [35] Gerasko O A, Samsonenko D G, Fedin V P. Russ. Chem. Rev., 2002,71:741-760
36. [36]
  [36] Sokolov M N, Dybtsev D N, Fedin V P. Russ. Chem. Bull., 2003,52:1041-1060
37. [37]
  [37] Ni X L, Lin J X, Zheng Y Y, et al. Cryst. Growth Des., 2008,8:3446-3450
38. [38]
  [38] Rekharsky M V, Yamamura H, Inoue C, et al. J. Am. Chem. Soc., 2006,128:14871-14880
39. [39]
  [39] Zhao Y J, Xue S F, Zhu Q J, et al. Chin. Sci. Bull., 2004, 49:1111-1116
40. [40]
  [40] Huang W H, Zavalij P Y, Isaacs L. J. Am. Chem. Soc., 2008,130:8446-8454
41. [41]
  [41] Jeon W S, Kim H J, Lee C, et al. Chem. Commun., 2002,17: 1826-1829
42. [42]
  [42] Trabolsi A, Hmadeh M, Khashab N M, et al. New J. Chem., 2009,33:254-263
43. [43]
  [43] Kang J K, Hwang I, Ko Y H, et al. Supramol. Chem., 2008, 20:149-155
44. [44]
  [44] Sobransingh D, Kaifer A E. Langmuir, 2006,22:10540-10544
45. [45]
  [45] Jeon W S, Moon K, Park S H, et al. J. Am. Chem. Soc., 2005,127:12984-12989
46. [46]
  [46] Mitkina T V, Zakharchuk N F, Naumov D Y, et al. Inorg. Chem., 2008,47:6748-6755
47. [47]
  [47] Hernandez-Molina R, Sokolov M, Esparza P, et al. Dalton Trans., 2004,6:847-851
48. [48]
  [48] Connors K A. Binding Constants. New York: Wiley, 1987.
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