Citation: HU Wen-Ting, ZHU Long-Guan. Study on the Synthesis, Crystal Structure and Catalytic Activity for Thioanisol of a Ruthenium Complex with 3-Sulfobenzoate and 2,2'-Bipyridine Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1109-1114. doi: 10.3969/j.issn.1001-4861.2013.00.191 shu

Study on the Synthesis, Crystal Structure and Catalytic Activity for Thioanisol of a Ruthenium Complex with 3-Sulfobenzoate and 2,2'-Bipyridine Ligands

1.
Department of Chemistry, Zhejiang University, Hangzhou 310027, China

Received Date: 15 November 2012
Available Online: 4 February 2013
Fund Project: 国家自然科学基金(No．21073157)资助项目。 (No．21073157)

The 2,2'-bipyridine-based ruthenium complex with sulfobenzoate ligand was synthesized, [Ru(2,2'-bipy)₃](3-Hsb)(3-sb)·5H₂O (1), where 2,2'-bipy is 2,2'-bipyridine and 3-sb^2- is 3-sulfobenzoate dianion, and characterized by elemental analysis, IR, UV-Vis, fluorescence spectrum, DTA-TG and single crystal X-ray analysis. The structural analysis showed that 1 is a cation-anion complex and the anions and water molecules form the three-dimensional hydrogen-bonding network with cavities occupied by cations. Cyclic voltammetry of 1 shows a one electron Ru(Ⅳ)/Ru(Ⅲ) reversible couple with E_1/2 of 1.350 V. The oxidation of thioanisol catalyzed by 1 together with the acid produced high yield and selectivity for the sulfoxide. CCDC: 910779.
- ruthenium complex;thioanisol;oxidation;crystal structure;cyclic voltammetry
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沈阳化工大学材料科学与工程学院沈阳 110142