Citation: LI Ming-Ji, WANG Xiu-Feng, LI Hong-Ji, WU Xiao-Guo, QU Chang-Qing, YANG Bao-He. Growth Characteristics of Single-Crystalline MgO Nanobelts and Its Photoluminescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1199-1205. doi: 10.3969/j.issn.1001-4861.2013.00.190 shu

Growth Characteristics of Single-Crystalline MgO Nanobelts and Its Photoluminescence Properties

1.
1. Tianjin Key Laboratory of Film Electronic and Communicate Devices, College of Electronics Information Engineering, Tianjin University of Technology, Tianjin 300384, China;

Received Date: 4 January 2012
Available Online: 5 March 2013
Fund Project: 国家自然科学基金(No.50972105) (No.50972105)天津市自然科学基金(No.10SYSYJC27700) (No.10SYSYJC27700)国家高技术研究发展计划(863)(No.2013AA030801)资助项目。 (863)(No.2013AA030801)

Single-crystal MgO nanobelts were synthesized by direct current (DC) arc plasma jet chemical vapor deposition (CVD) on Mo substrates. An attempt has been made to prepare MgO nanobelts through decomposition of magnesium nitrate under argon and hydrogen flow at 950 ℃ for different durations. The MgO nanobelts were characterized by scanning electron microscopy (SEM), high resolution transmission electron microscopy (HRTEM), and powder X-ray diffraction (XRD) pattern. When reaction time was increased from 0.5 to 12 min, the initially formed “tadpole-like” MgO nanostructures transformed into “dendrite-like” structures, nanobelts, and finally nanorods. The “tadpole-like” nanostructures are mainly belts with Mo nanoparticles capped at the MgO nanobelts’ ends, and the nanostructure is covered by an amorphous layer. The nanobelts prepared after 5 min with widths ranging from 30 to 50 nm. The growth of MgO nanobelts was initiated by Mo catalyst nanoparticles via a catalyst-assisted vapor-liquid-solid (VLS) process, and a side growth along the belt width direction via a vapor-solid (VS) process was also suggested. Moreover, the MgO nanobelts exhibited strong ultraviolet-blue emission. The strong optical properties were correlated with large surface area and presence of oxide ions in low coordination (LC) O_LC^2- (where LC=5C, 4C and 3C for terrace, edge, corner and kink sites, respectively) along with defects, which was revealed by fourier transform Infrared (FTIR) spectrometer and photoluminescence (PL) spectroscopy studies. Our group for the first time reported the DC arc plasma jet CVD method to obtain single crystalline MgO nanobelts, which possesses the advantages of being simple, economical, fast, effective and environmentally benign.
- DC arc plasma jet CVD;MgO;nanobelts;photoluminescence
1. [1]
  [1] Shah M A, Al-Marzouki F M. Int. J. Biomed. Nanosci. Nanotechnol., 2010,1(1):10-16
2. [2]
  [2] Zhu K K, Hua W M, Deng W, et al. Eur. J. Inorg. Chem., 2012,2012(17):2869-2876
3. [3]
  [3] YANG Xiao-Long(杨晓龙), XIA Chun-Gu(夏春谷), TANG Li-Ping(唐立平), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(8):1541-1549
4. [4]
  [4] KONG Meng(孔猛), YANG Qi(杨琦), LU Wen(卢雯), et al. Chin. J. Catal.(Cuihua Xuebao), 2012,33(9):1508-1516
5. [5]
  [5] YANG Wen(杨文), CHU Wei(储伟), JIANG Cheng-Fa (江成发), et al. Chin. J. Catal.(Cuihua Xuebao), 2011,32(8): 1323-1328
6. [6]
  [6] Zhang J, Zhang L, Peng X, et al. Appl. Phys. A: Mater. Sci. Process, 2001,73(6):773-775
7. [7]
  [7] LU Qi-Fang(卢启芳), LIU Su-Wen(刘素文). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(10):2066-2070
8. [8]
  [8] LI Jie-Bin(李节宾), XU You-Long(徐友龙), XIONG Li-Long (熊礼龙), et al. Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2011,27(11):2593-2599
9. [9]
  [9] Jung C H, Lee J Y, Yoon D H. J. Nanosci. Nanotechnol., 2012,12(2):1700-1704
10. [10]
  [10] Peidong Y, Lieber C M. Science, 1996,273(5283):1836-1840
11. [11]
  [11] Kumar A, Kumar J, Priya S. Appl. Phys. Lett., 2012, 100(19):192404
12. [12]
  [12] Kim J, Gila B, Mehandru R, et al. J. Electrochem. Soc., 2002,149(8):G482-G484
13. [13]
  [13] Umar A, Rahman M M, Hahn Y B. Electrochem. Commun., 2009,11(7):1353-1357
14. [14]
  [14] Zhao J W, Qin L R, Hao Y H, et al. Microchim. Acta, 2012,178(3/4):439-445
15. [15]
  [15] Wee S H, Goyal A, MORE K L, et al. Nanotechnology, 2009,20(21):215608
16. [16]
  [16] Zhang J, Zhang L D. Chem. Phys. Lett., 2002,363(3/4): 293-297
17. [17]
  [17] Li Y B, Bando Y, Sato T. Chem. Phys. Lett., 2002,359 (1/2):141-145
18. [18]
  [18] Ma R Z, Bando Y. Chem. Phys. Lett., 2003,370(5/6):770-773
19. [19]
  [19] CHEN Chen(陈晨), ZHUANG Jing(庄京), WANG Ding- Sheng(王定胜), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2005,21(6):859-861
20. [20]
  [20] Shi Q Z, Liu Y C, Gao Z M, et al. J. Mater. Sci., 2008,43 (4):1438-1443
21. [21]
  [21] Fang X S, Ye C H, Zhang L D, et al. Small, 2005,1(4): 422-428
22. [22]
  [22] Hao Y F, Meng G W, Zhou Y, et al. Nanotechnology, 2006,17(19):5006-5012
23. [23]
  [23] ZHAI Hua-Zhang(翟华嶂), AN Xiao-Qiang(安晓强), CAO Chuan-Bao(曹传宝), et al. Rare Metal Mater. Eng. (Xiyou Jinshu Cailiao Yu Gongcheng), 2008,37(S1):667-670
24. [24]
  [24] Gao T, Wang T. J. Phys. Chem. B, 2004,108(52): 20045- 20049
25. [25]
  [25] Sutradhar N, Sinhamahapatra A, Pahari S K, et al. J. Phys. Chem. C, 2011,115(25):12308-12316
26. [26]
  [26] Sutradhar N, Sinhamahapatra A, Roy A B, et al. Mater. Res. Bull., 2011,46(11):2163-2167
27. [27]
  [27] Selvamani T, Sinhamahapatra A, Bhattacharjya D, et al. Mater. Chem. Phys., 2011,129(3):853-861
28. [28]
  [28] Selvam N C S, Kumar R T, Kennedy L J, et al. J. Alloys Compd., 2011,509(41):9809-9815
29. [29]
  [29] Gribov E N, Bertarione S, Scarano D, et al. J. Phys. Chem. B, 2004,108(41):16174-16186
30. [30]
  [30] Kumar A, Thota S, Varma S, et al. J. Lumin., 2011,131(4): 640-648
31. [31]
  [31] Sterrer M, Berger T, Diwald O, et al. J. Am. Chem. Soc., 2002,125(1):195-199
32. [32]
  [32] Wu M C, Truong C M, Goodman D W. Phys. Rev. B: Condens. Matter. Mater. Phys., 1992,46(19):12688-12694
33. [33]
  [33] Trevisanutto P E, Sushko P V, Shluger A L, et al. Surf. Sci., 2005,593(1/2/3):210-220
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