Citation: RONG Zhong-Hua, MA Yun-Sheng, TANG Xiao-Yan, YUAN Rong-Xin, XIE Ji-Min. Terephthalate Derivatives as Links in the Construction of Two Novel Cd(Ⅱ) Coordination Polymers[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1249-1254. doi: 10.3969/j.issn.1001-4861.2013.00.189 shu

Terephthalate Derivatives as Links in the Construction of Two Novel Cd(Ⅱ) Coordination Polymers

1.
1. School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China;

Received Date: 23 December 2012
Available Online: 27 February 2013
Fund Project: 国家自然科学基金(No.21001018,No.21201025)。江苏省高校自然科学重大项目(No.12KJA150001)。江苏省科技基础研究计划 (No.BK2012643)资助项目。 (No.21001018,No.21201025)。江苏省高校自然科学重大项目(No.12KJA150001)。江苏省科技基础研究计划 (No.BK2012643)

Two novel cadmium coordination polymers: Cd(BrBDC)(py) (1) and Cd(NH₂BDC)(H₂O) (2) (BrBDC=2-bromo-1,4-benzenedicarboxylate, NH₂BDC=2-amino-1,4-benzenedicarboxylate, py=pyridine), were synthesized under solvothermal conditions. The crystal structure of Cd(BrBDC)(py) is based on infinite chains of carboxylato-bridged six coordinated Cd(Ⅱ) ions that are linked via the BrBDC ligands to form a 2D structure. Cd(NH₂BDC)(H₂O) is based on brick-like 2D layers constructed by carboxylato that are crosslinked by the amino groups into a 3D structure. The photoluminescence of both compounds are studied. CCDC: 915674, 1; 915673, 2.
- coordination polymer;crystal structure;cadmium;terephthalic acid
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沈阳化工大学材料科学与工程学院沈阳 110142