Citation: ZHAO Li-Na, CHEN Lin, LIU Bo, LI Xiu-Mei, WANG Qing-Wei. Hydrothermal Synthesis and Crystal Structure of Two Three-Dimensional Supramolecular Lead(Ⅱ) Coordination Polymers[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1243-1248. doi: 10.3969/j.issn.1001-4861.2013.00.188 shu

Hydrothermal Synthesis and Crystal Structure of Two Three-Dimensional Supramolecular Lead(Ⅱ) Coordination Polymers

1.
1. Key Laboratory of Preparation and Applications of Environmental Friendly Materials Ministry of Education, Jilin Normal University, Siping, Jilin 136000, China;

Received Date: 29 October 2012
Available Online: 25 February 2013
Fund Project: 吉林省教育厅科学技术研究(吉教科合字[2012]第358号)资助项目。 (吉教科合字[2012]第358号)

Two new metal-organic coordination polymers [Pb(NA)L]_n 1, [Pb(CH₃COO)L]_n·nH₂O 2 (H₂NA=nicotinic acid, L=2-(4-nitrophenol)-1H-imidazo[4,5-f][1,10]phenanthroline) have been hydrothermally synthesized and structurally characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. They are further extended into a three-dimensional supramolecular network structure through hydrogen-bonding and π-π interactions. Moreover, the luminesent property of 1 and 2 have been investigated in the solid state. CCDC: 931504, 1; 931505, 2.
- hydrothermal synthesis;crystal structure;lead complex
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沈阳化工大学材料科学与工程学院沈阳 110142