Citation: HUANG Ying-Juan, ZHOU Xiao-Yan, LI Zai-Jun, GU Zhi-Guo, WANG Guang-Li. Seed-Mediated Synthesis of Size-Tunable and Monodisperse Gold Nanorods through the Use of Anionic Surfactant as Additives[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1141-1148. doi: 10.3969/j.issn.1001-4861.2013.00.186 shu

Seed-Mediated Synthesis of Size-Tunable and Monodisperse Gold Nanorods through the Use of Anionic Surfactant as Additives

1.
1. School of Chemical and Material Engineering, Jiangnan University;

Received Date: 28 December 2012
Available Online: 31 January 2013
Fund Project: 国家自然科学基金 (No.21176101) (No.21176101)国家科技支撑计划(No.2011BAK10B032) (No.2011BAK10B032)

Different anionic surfactant was empolyed as additive for the seed-mediated synthesis of gold nanorods and effect of the kind of anionic surfactant on the morphology and optical property of gold nanorods were also investigated. In the presence of sodium dodecyl benzene sulfonate (SDBS), the yield of gold nanorods is obviously higher that of the reaction system using sodium dodecyl sulfate. The reaction conditions of the seed-mediated synthesis of gold nanorods added SDBS were optimized, and the optimal concentrations of hexadecyltrimethylammonium bromide, SDBS, ascorbic acid and silver nitrate were found to be 0.04 mol·L^-1, 2.4 mmol·L^-1, 1.2 mmol·L^-1 and 0.08 mmol·L^-1, respectively. Under the condition, the growth of gold nanorods can complete within 30 minutes, the as-prepared gold nanorods offer a surface plasmon resonance absorption with a maximum absorption peak at 823 nm and aspect ratio of (5±0.03). When changing silver nitrate concentration in the growth solution, the size of gold nanorods also changed. In addition, we also discussed the action mechanism of SDBS. In comparsion with classical seed-mediated synthesis method, proposed method for synthesis of gold nanorods shows an obvious improvement of size adjustable, monodispersity and biological toxicity, and it can be widely applied to a variety of optical and biological analysis.
- anionic surfactant;sodium dodecyl benzene sulfonate;gold nanorods;monodispersity;size-tunable
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