Citation: XUE Min, LIU Shi-Xiong. Synthesis and Crystal Structure of Dinuclear Metal Complexes with Schiff Base Ligand of Bis-salicylaldehyde[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1319-1327. doi: 10.3969/j.issn.1001-4861.2013.00.185 shu

Synthesis and Crystal Structure of Dinuclear Metal Complexes with Schiff Base Ligand of Bis-salicylaldehyde

XUE Min ¹ ,
LIU Shi-Xiong ²

1.
1. School of Chemistry and Chemical Engineering, Xian Univeristy of Arts and Science, Xi'an 710065, China;

Received Date: 26 November 2012
Available Online: 4 March 2013
Fund Project: 西安文理学院院级重大课题(No.zd201003)资助项目。 (No.zd201003)

Four dinuclear transition metal complexes with schiff base ligand of bis-salicylaldehyde have been synthesized and structurally characterized by means of elemental analysis, IR, UV, TGA and X-ray single-crystal diffraction. The results of structural analysis indicate that complex 1, 3 and 4 belong to triclinic crystal system, space group P1 and the complex 2 belong to monoclinic crystal system, space group C2/c. In complex 1, two copper ions show different coordination environment, one of which has a five-coordinate, slightly distorted tetragonal pyramidal geometry and another has a four-coordinate squareplanar geometry. In complex 4, the binuclear units are held together to form an infinite 1D chain by bridging phenol O atoms.
- Schiff base;dinuclear metal complexes;crystal structures
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