Citation: ZHENG Jian-Dong, GE Xiu-Tao. Perovskite-Type SrFe_1-xMn_xO₃ Catalysts: Preparation by Co-precipitation Method and Catalytic Performance for Methane Combustion[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1307-1311. doi: 10.3969/j.issn.1001-4861.2013.00.183 shu

Perovskite-Type SrFe_1-xMn_xO₃ Catalysts: Preparation by Co-precipitation Method and Catalytic Performance for Methane Combustion

1.
College of Material and Chemical Engineering, Chuzhou University, Chuzhou, Anhui 239012, China

Received Date: 5 October 2012
Available Online: 8 March 2013
Fund Project: 安徽省教育厅自然科学研究重点项目(No.KJ2012A213) (No.KJ2012A213) 安徽省教育厅教研项目(No.2012jyxm534) (No.2012jyxm534) 安徽省应用化学重点学科(No. 200802187C)资助项目。 (No. 200802187C)

Manganese substituted ferric perovskite-type catalysts were prepared by co-precipitation method. The title catalysts were calcined at 700 ℃ and characterized by XRD, TPR and TG-DSC techniques. The catalytic activity was evaluated using methane combustion as a model reaction. The specific surface area was calculated by BET model. The values of the apparent activation energy were estimated from the Arrhenius plots based on a CH₄ first-order rate equation. The samples exhibit significant catalytic activity for methane combustion at 700 ℃. With increasing the substitution of Mn²⁺, the activities of the catalysts are improved. Upon calcination at 700 ℃ the catalyst SrMnO₃ shows an excellent activity for methane combustion (the conversion of 10% and 90% are obtained at 435 ℃ and 457 ℃, respectively).
- materials science;perovskite;catalytic activity
1. [1]
  [1] Gelin P, Primet M. Appl Catal. B, 2002,39:1-37
2. [2]
  [2] Gao Z M, Wang R Y. Appl.Catal. B, 2010,98:147-153
3. [3]
  [3] Choudhary TV, Banerjee S, Choudhary VR. Appl. Catal. A, 2002,234:1-23
4. [4]
  [4] Kimura K, Ohgaki M, Tanaka K, et al. J. Solid. State Chem., 1990,87:186-194
5. [5]
  [5] Shaheen M, Selim M. J. Therm. Anal. Calorim., 2000,59:61 -70
6. [6]
  [6] Alegre V, Silva P, Schmal M. Catal. Commun., 2006,7:14-22
7. [7]
  [7] Ferri D, Forni L. Appl. Catal. B, 1998,16:119-123
8. [8]
  [8] Kirchnerova J, Alifanti M, Delmon B. Appl. Catal. A, 2002, 231:65-69
9. [9]
  [9] Valange S, Beauchaud A, Barrault J, et al. J. Catal., 2007, 251:113-122
10. [10]
  [10] Petrovic S, Terlecki A, Karanovic L, et al. Appl. Catal. B, 2008,79:186-192
11. [11]
  [11] Spinicci R, Tofanari A, Delmastro A, et al. Mater. Chem. Phys., 2002,76:20-24
12. [12]
  [12] Batiot-Dupeyrat C, Martinez-Ortega F, Ganne M. Appl. Catal. A, 2001,206:205-211
13. [13]
  [13] Jang B W, Nelson R M, Spivey J J. Catal. Today, 1999,47: 103-113
14. [14]
  [14] Zheng J D, Ren X G. React. Kinet. Catal. Lett., 2008,93:3-9
15. [15]
  [15] Groppi G, Cristiani C. Appl. Catal. B: Environmental, 2001,35:137-141
16. [16]
  [16] ZHENG Jian-Dong(郑建东), REN Xiao-Guang(任晓光). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012,28: 823-828
17. [17]
  [17] Stobbe E R, de Boer B A, Geus J W. Catal. Today, 1999,47:161-167
18. [18]
  [18] HOU Hong-Xia(侯红霞), JIANG Zheng(蒋政), SU Ji-Xin (苏继新). Advances in Fine Petrochemicals (Jingxi Shiyou Huagong Jinzhan), 2004,5:1-6
19. [19]
  [19] Astier M, Garbowski E, Primet M. Catal. Lett., 2004,95:1-7
1. [1]
  Yao Ma , Xin Zhao , Hongxu Chen , Wei Wei , Liang Shen . Progress and Perspective of Perovskite Thin Single Crystal Photodetectors. Acta Physico-Chimica Sinica, 2025, 41(4): 100030-. doi: 10.3866/PKU.WHXB202309045
2. [2]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
3. [3]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
4. [4]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
5. [5]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
6. [6]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011
7. [7]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
8. [8]
  Jian Li , Yu Zhang , Rongrong Yan , Kaiyuan Sun , Xiaoqing Liu , Zishang Liang , Yinan Jiao , Hui Bu , Xin Chen , Jinjin Zhao , Jianlin Shi . 高效靶向示踪钙钛矿纳米系统光电增效抗肿瘤. Acta Physico-Chimica Sinica, 2025, 41(5): 100042-. doi: 10.1016/j.actphy.2024.100042
9. [9]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
10. [10]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
11. [11]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
12. [12]
  Xiaoyao YIN , Wenhao ZHU , Puyao SHI , Zongsheng LI , Yichao WANG , Nengmin ZHU , Yang WANG , Weihai SUN . Fabrication of all-inorganic CsPbBr₃ perovskite solar cells with SnCl₂ interface modification. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 469-479. doi: 10.11862/CJIC.20240309
13. [13]
  Zeyi Yan , Ruitao Liu , Xinyu Qi , Yuxiang Zhang , Lulu Sun , Xiangyuan Li , Anchao Feng . Exploration of Suspension Polymerization: Preparation and Fluorescence Stability of Perovskite Polystyrene Microbeads. University Chemistry, 2025, 40(4): 72-79. doi: 10.12461/PKU.DXHX202405110
14. [14]
  Pengyu Dong , Yue Jiang , Zhengchi Yang , Licheng Liu , Gu Li , Xinyang Wen , Zhen Wang , Xinbo Shi , Guofu Zhou , Jun-Ming Liu , Jinwei Gao . NbSe₂纳米片优化钙钛矿太阳能电池的埋底界面. Acta Physico-Chimica Sinica, 2025, 41(3): 2407025-. doi: 10.3866/PKU.WHXB202407025
15. [15]
  Zhiliang Li . An Overview of Research on the History of Catalysis Science in China. University Chemistry, 2024, 39(7): 398-404. doi: 10.3866/PKU.DXHX202310101
16. [16]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
17. [17]
  Zhenming Xu , Yibo Wang , Zhenhui Liu , Duo Chen , Mingbo Zheng , Laifa Shen . Experimental Design of Computational Materials Science and Computational Chemistry Courses Based on the Bohrium Scientific Computing Cloud Platform. University Chemistry, 2025, 40(3): 36-41. doi: 10.12461/PKU.DXHX202403096
18. [18]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
19. [19]
  Yadan Luo , Hao Zheng , Xin Li , Fengmin Li , Hua Tang , Xilin She . 调节O,S共掺杂C₃N₄中的活性氧生成以促进光催化降解微塑料. Acta Physico-Chimica Sinica, 2025, 41(6): 100052-. doi: 10.1016/j.actphy.2025.100052
20. [20]
  Pengcheng Yan , Peng Wang , Jing Huang , Zhao Mo , Li Xu , Yun Chen , Yu Zhang , Zhichong Qi , Hui Xu , Henan Li . Engineering Multiple Optimization Strategy on Bismuth Oxyhalide Photoactive Materials for Efficient Photoelectrochemical Applications. Acta Physico-Chimica Sinica, 2025, 41(2): 100014-. doi: 10.3866/PKU.WHXB202309047

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(423)
HTML views(69)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Perovskite-Type SrFe1-xMnxO3 Catalysts: Preparation by Co-precipitation Method and Catalytic Performance for Methane Combustion

Metrics

通讯作者: 陈斌, bchen63@163.com

Perovskite-Type SrFe_1-xMn_xO₃ Catalysts: Preparation by Co-precipitation Method and Catalytic Performance for Methane Combustion