Citation: ZHENG Jian-Dong, GE Xiu-Tao. Perovskite-Type SrFe_1-xMn_xO₃ Catalysts: Preparation by Co-precipitation Method and Catalytic Performance for Methane Combustion[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1307-1311. doi: 10.3969/j.issn.1001-4861.2013.00.183 shu

Perovskite-Type SrFe_1-xMn_xO₃ Catalysts: Preparation by Co-precipitation Method and Catalytic Performance for Methane Combustion

1.
College of Material and Chemical Engineering, Chuzhou University, Chuzhou, Anhui 239012, China

Received Date: 5 October 2012
Available Online: 8 March 2013
Fund Project: 安徽省教育厅自然科学研究重点项目(No.KJ2012A213) (No.KJ2012A213) 安徽省教育厅教研项目(No.2012jyxm534) (No.2012jyxm534) 安徽省应用化学重点学科(No. 200802187C)资助项目。 (No. 200802187C)

Manganese substituted ferric perovskite-type catalysts were prepared by co-precipitation method. The title catalysts were calcined at 700 ℃ and characterized by XRD, TPR and TG-DSC techniques. The catalytic activity was evaluated using methane combustion as a model reaction. The specific surface area was calculated by BET model. The values of the apparent activation energy were estimated from the Arrhenius plots based on a CH₄ first-order rate equation. The samples exhibit significant catalytic activity for methane combustion at 700 ℃. With increasing the substitution of Mn²⁺, the activities of the catalysts are improved. Upon calcination at 700 ℃ the catalyst SrMnO₃ shows an excellent activity for methane combustion (the conversion of 10% and 90% are obtained at 435 ℃ and 457 ℃, respectively).
- materials science;perovskite;catalytic activity
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Perovskite-Type SrFe1-xMnxO3 Catalysts: Preparation by Co-precipitation Method and Catalytic Performance for Methane Combustion

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通讯作者: 陈斌, bchen63@163.com

Perovskite-Type SrFe_1-xMn_xO₃ Catalysts: Preparation by Co-precipitation Method and Catalytic Performance for Methane Combustion