Citation: TIAN Li, ZHOU Shang-Yong. Crystal Structures and Properties of Two Novel Copper Compounds Constructed from Bistriazole Methane[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1255-1262. doi: 10.3969/j.issn.1001-4861.2013.00.178 shu

Crystal Structures and Properties of Two Novel Copper Compounds Constructed from Bistriazole Methane

TIAN Li ,
ZHOU Shang-Yong

1.
Tianjin Key Laboratory of Structure and Performance for Functional Molecules; Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education; College of Chemistry, Tianjin Normal University, Tianjin 300387, China

Received Date: 6 July 2012
Available Online: 1 March 2013
Fund Project: 天津市自然科学基金(No.12JCZDJC27600)资助项目。 (No.12JCZDJC27600)

Using a flexible bis-triazole ligand bis(1,2,4-triazol-1-y1)metane (btm), two new copper(Ⅱ) coordination polymers [Cu_0.5(btm)Cl]_n (1) and [Cu(btm)Cl₂]_n (2) have been synthesized under hydrothermal conditions. The coordinating mode of chlorine anions can be tuned as a result of changing the metal/ligand ratio in the reaction system, which ultimately forms two novel structures. 1 possesses infinite 1D chain structure, and uncommonly four-fold Cl…H-C hydrogen bonds help the chains form a 3D supramolecular architecture. 2 features 2D (4.4) net framewok. Hydrogen bonds (Cl…H-C) reside among the 2D layers, which link the 2D layers to lead to a 3D supramolecular architecture. For 1 and 2, X-ray crystallography, elemental analysis, thermal stability and EPR spectra have been carried out. CCDC: 932333, 1; 932332, 2.
- Cu(Ⅱ) complex;crystal structure;bis(1,2,4-triazol-1-y1)metane
1. [1]
  [1] Savaki T, Dewa T, Aoyama Y. J. Am. Chem. Soc., 1998,120: 8539-8540
2. [2]
  [2] De Sá G F, Malta O L, Mello Donegá C de, et al. Coord. Chem. Rev., 2000,196:165-195
3. [3]
  [3] Ikkala O, Brinke G. Science, 2002,295:2407-2409
4. [4]
  [4] Ishikava N, Sugita M, Ishikawa T, et al. J. Am. Chem. Soc., 2003,125:8694-8695
5. [5]
  [5] Zhang J P, Lin Y Y, Zhang W X, et al. J. Am. Chem. Soc., 2005,127:14162-14163
6. [6]
  [6] Kitagawa S, Noro S I, Nakamura T, Chem. Commun., 2006, 11:701-707
7. [7]
  [7] Kepert C J. Chem. Commun., 2006,11:695-700
8. [8]
  [8] Morris W, Doonan C J, Furukawa H, et al. J. Am. Chem. Soc., 2008,130:12626-12627
9. [9]
  [9] Ockwig N W, Delgado-Friedrichs O, O'Keeffe M, et al. Acc. Chem. Res., 2005,38:176-182
10. [10]
  [10] Biradha K, Sarkar M, Rajput L. Chem. Commun., 2006,11: 4169-4179
11. [11]
  [11] Ye B H, Tong M L, Chen X M. Coord. Chem. Rev., 2005, 249:545-565
12. [12]
  [12] SUN Hai-Xia(孙海霞), LIU Dong-Ju(刘冬菊), ZHANG Yan (张琰), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(10):2205-2210
13. [13]
  [13] Albada G V, Guijt R C, Haasnoot J G, et al. Eur. J. Inorg. Chem., 2000:121-126
14. [14]
  [14] Garcia Y, Koningsbruggen van P J, Bravic G, et al. Eur. J. Inorg. Chem., 2003:356-362
15. [15]
  [15] Liu J C, Fu D G, Zhuang J Z, et al. Dalton Trans., 1999,29: 2337-2342
16. [16]
  [16] Hagrman P J, Bridges C, Greedan J E, et al. Dalton Trans., 1999,29:2901-2903
17. [17]
  [17] Drabent K, Ciunik Z. Chem. Commun., 2001,6:1254-1255
18. [18]
  [18] Yi L, Ding B, Zhao B, et al. Inorg. Chem., 2004,43:33-43
19. [19]
  [19] Li B, Zhu X, Zhou J, et al. Polyhedron, 2004,23:3133-3141
20. [20]
  [20] Wang X, Li B, Zhu X, et al. Eur. J. Inorg. Chem., 2005: 3277-3286
21. [21]
  [21] Huang Y Q, Ding B, Song H B, et al. Chem. Commun., 2006,11:4906-4908
22. [22]
  [22] Zhu X, Ge H, Zhang Y, et al. Polyhedron, 2006,25:1875- 1883
23. [23]
  [23] Ding J G, Ge H Y, Zhang Y M, et al. J. Mol. Struct., 2006, 782:143-149
24. [24]
  [24] Ding B, Huang Y Q, Liu Y Y, et al. Inorg. Chem. Commun., 2007,10:7-10
25. [25]
  [25] Tian A X, Ying J, Peng J, et al. Cryst. Growth Des., 2008,8: 3717-3724
26. [26]
  [26] Habib H A, Hoffmann A, Höppea H A, et al. Dalton Trans., 2009,39:1742-1751
27. [27]
  [27] Tian L, Zhang Z J, Yu A, et al. Cryst. Growth Des., 2010, 10:3847-3849
28. [28]
  [28] Tian L, Yang N, Zhao G Y. Inorg. Chem. Commun., 2010, 14:1497-1500
29. [29]
  [29] Yang E C, Feng W, Wang J Y, et al. Inorg. Chim. Acta, 2010,363:308-316
30. [30]
  [30] DING Bin(丁斌), CHANG Ruo-Nan(常若男), WU Xiang- Xia(吴向侠), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(1):189-192
31. [31]
  [31] DU Xiao-Di(杜晓迪), LI Chun-Yang(李春阳), CHANG Jia- Zhong(常加忠), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(10):2223-2228
32. [32]
  [32] Tian L, Chen Z, Yu A, et al. CrystEngComm., 2012,14:2032 -2039
33. [33]
  [33] Torres J, Lavandera J L, Cabildo P, et al. J. Heterocyc. Chem., 1988,25:771-782
34. [34]
  [34] Wu G, Wang X F, Okamura T A, et al. Inorg. Chem., 2006, 45:8523-8532
35. [35]
  [35] Gu Z G, Xu Y F, Zhou X H, et al. Cryst. Growth Des., 2008,8:1306-1312
36. [36]
  [36] Bronisz R. Inorg. Chem., 2005,44:4463-4465
37. [37]
  [37] Tian A X, Ying J, Peng J, et al. Inorg. Chem., 2009,48:100- 110
38. [38]
  [38] Thakurta S, Roy P, Rosair G, et al. Polyhedron, 2009,28: 695-702
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