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Citation: WU Dan-Ni, WU Xiao-Mei, ZENG Xiao-Qin, LI Fei, SU Xin, ZOU Jian-Xin, DING Wen-Jiang. Electrochemical Studies of Substituted Cu2Mo6S8-nSen for Rechargeable Magnesium Battery[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1103-1108. doi: 10.3969/j.issn.1001-4861.2013.00.177 shu

Electrochemical Studies of Substituted Cu2Mo6S8-nSen for Rechargeable Magnesium Battery

  • 1.

    1. Shanghai Engineering Research Center of Magnesium Materials and Applications, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China;

  • Received Date: 18 December 2012
    Available Online: 11 February 2013

    Fund Project: 国家自然科学基金 (No.51274140) (No.51274140)高等学校博士点基金课题(20110073130001)资助项目。 (20110073130001)

  • The Chevrel Phase materials Cu2Mo6S8-nSen (n=0,0.5,1.5) were synthesized by molten salt methods. Their crystal structures and the electrochemical properties were studied by a combination of X-ray diffraction (XRD), scanning electron microscopy (SEM), cyclic voltammetry test (CV), galvanostatic charge-discharge test and electrochemical impedance spectroscopy (EIS). XRD analysis showed that Se-substituted Cu2Mo6S8-nSen was still Chevrel Phase, however the lattice parameters became larger, and SEM pictures viewed the particle size was small. The studies of the electrochemical properties suggested that the shape of voltammetric peaks in the region 0.5～0.8 V changed, the steady specific capacity increased to 103.5 mAh·g-1 and the cycling performance were improved because of Se substituted in Cu2Mo6S8. All these proved the reversible intercalation of Mg ions into these hosts were facilitated.
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    1. [1]

      [1] Gregory T D, Hoffman R J, Wubterton R J. J. Electrochem. Soc., 1990,137:775-780

    2. [2]

      [2] SHEN Jian(沈健), PENG Bo(彭博), TAO Zhan-Liang (陶占良), et al. Prog. Chem. (Huaxue Jinzhan), 2010,22(2/3): 515-521

    3. [3]

      [3] FENG Zhen-Zhen(冯真真). Thesis for the Doctorate of Shanghai Jiaotong University(上海交通大学博士论文). 2008.

    4. [4]

      [4] Novak P, Imhof R, Haas O. Electrochim. Acta, 1999,45:351 -367

    5. [5]

      [5] Aurbach D, Weissman I, Gofer Y, et al. Chem. Rec., 2003,3: 61-73

    6. [6]

      [6] Makino K, Katayama Y, Miura T, et al. J. Power Sources, 2002,112:85-89

    7. [7]

      [7] FENG Zhen-Zhen(冯真真), NULI Yan-Na(努丽燕娜), YANG Jun(杨军). Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2007,23(3):327-331

    8. [8]

      [8] LI Yun(李云), NuLI Yan-Na(努丽燕娜), YANG Jun(杨军), et al. Chin. J. Power Sources(Dianyuan Jishu), 2010,34(10): 1031-1034

    9. [9]

      [9] NULI Yan-Na(努丽燕娜), YANG Jun(杨军), ZHENG Yu-Pei (郑育培), et al. J. Inorg. Mater.(Wuji Cailiao Xuebao), 2011,26(2):129-133

    10. [10]

      [10] GAO Xiu-Ling(高秀玲), JIAO Li-Fang(焦丽芳), YUAN Huan- Tang(袁华堂), et al. Electrochem. (Dianhuaxue), 2005,11: 337- 339

    11. [11]

      [11] YUAN Huan-Tang(袁华堂), CAO Jian-Sheng(曹建胜), WANG Yi-Jing(王一菁), et al. Chem. J. Chinese Universities(Gaodeng Xuexiao Huaxue Xuebao), 2001, 22:16-18

    12. [12]

      [12] ZHAO Ming(赵敏), JIAO Li-Fang(焦丽芳), YUAN Huan- Tang(袁华堂), et al. Acta Sci. Natura. Univ. Nankaiensis (NanKai Daxue Xuebao: Ziran Kexue Ban), 2006,39(3):39-42

    13. [13]

      [13] Cheverl R, Sergent M, Prigent J, et al. Solid. State. Chem., 1971,3:515-519

    14. [14]

      [14] Aurbach D, Lu Z, Schechteretal A, et al. Nature, 2000,407: 724-726

    15. [15]

      [15] Levi E, Lancry E, Mitelman A, et al. Chem. Mater., 2006, 18:5492-5503

    16. [16]

      [16] Levi E, Lancry E, Mitelman A, et al. Chem. Mater., 2006,18: 3705-3714

    17. [17]

      [17] Levi E, Lancry E, Mitelman A, et al. Inorg. Chem., 2008,47: 1975-1983

    18. [18]

      [18] Lancry E, Levi E, Gofer Y, et al. Chem. Mater., 2004,16: 2832-2838

    19. [19]

      [19] Mitelman A. Lithium-Ion Batteries: Materials and Devices 210th ECS Meeting. Levi E, Lancry E., Cancum,Mexico: Electrochem. Soc. Inc, 2007:109-115

    20. [20]

      [20] Levi E, Mitelman A, Aurbach D, et al. Chem. Mater., 2007, 19:5131- 5142

    21. [21]

      [21] Mitelman A, Levi M D, Lancry E, et al. Chem. Comm., 2007: 4212-4214

    22. [22]

      [22] LI Fei(李斐), WU Xiao-Mei(吴晓梅), ZENG Xiao-Qin (曾小勤), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28:1310-1314

    23. [23]

      [23] Suresh G S, Levi M D, Aurbach D. Electrochimica. Acta, 2008,53:3889-3896

    24. [24]

      [24] Johnson D C, Tarascon J M, Sienko M J. Inorg. Chem., 1983, 22:3773

    25. [25]

      [25] Levi M D, Lancry E, Levi E, et al. Solid State Ionics, 2005, 176:1695-1699

    26. [26]

      [26] Levi M D, Gizbar H, Lancry E, et al. J. Electroanal. Chem., 2004,569:211-223

    27. [27]

      [27] Aurbach D, Levi M D, Levi E. Solid State Ionics, 2008,179: 742-751

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