Citation: LI Xiu-Mei, JI Jian-Ye, NIU Yan-Ling, WANG Qing-Wei, WANG Zhi-Tao. Hydrothermal Synthesis and Crystal Structure of a 2D Network Mn(Ⅱ) Coordination Polymer Based on Oxalic Acid and Bis(imidazol) Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1302-1306. doi: 10.3969/j.issn.1001-4861.2013.00.171 shu

Hydrothermal Synthesis and Crystal Structure of a 2D Network Mn(Ⅱ) Coordination Polymer Based on Oxalic Acid and Bis(imidazol) Ligands

1.
1. Department of Chemistry, Tonghua Teachers College, Tonghua, Jilin 134002, China;

Received Date: 23 May 2012
Available Online: 30 January 2013
Fund Project: 吉林省科技发展计划(No.201205080)资助项目。 (No.201205080)

A new metal-organic coordination polymer [Mn(C₂O₄)(bimb)]_n·0.25nH₂O (1) (H₂C₂O₄=oxalic acid, bimb=1,4-bis(imidazol-1-yl)-butane) has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, UV spectrum, TG and single-crystal X-ray diffraction. The title compound crystallizes in the triclinic system, space group P1 with a=0.928 62(12) nm, b=0.965 61(13) nm, c=0.972 27(13) nm, α=67.992(2)°, β=87.361(2)°, γ=64.596(2)°, V=0.723 25(17) nm³, C₂₄H₂₉Mn₂N₈O_8.5, M_r=675.43, D_c=1.551 g·cm^-3, μ(Mo Kα)=0.936 mm^-1, F(000)=347, Z=1, R=0.031 2, wR=0.074 9. In the crystalstructure, the manganese atom is six-coordinated with four carboxylate oxygen atoms from two different C₂O₄^2- ligands and two nitrogen atoms from two bimb ligands, showing a distorted octahedral geometry. CCDC: 929937.
- hydrothermal synthesis;crystal structure;coordination polymer
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沈阳化工大学材料科学与工程学院沈阳 110142