Citation: LI Kai-Hui, XU Kai, MEI Shi-Le, RAO Dan-Ling, MEI Chong-Zhen. Synthesis, Structure and Luminescence Property of Cd(Ⅱ) Coordination Polymer Based on 4-Methylphthalic Acid and 4,4'-Bipyridine Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1312-1318. doi: 10.3969/j.issn.1001-4861.2013.00.164 shu

Synthesis, Structure and Luminescence Property of Cd(Ⅱ) Coordination Polymer Based on 4-Methylphthalic Acid and 4,4'-Bipyridine Ligand

1.
1. Institute of Environmental and Municipal Engineering, North China University of Water Conservancy and Electric Power, Zhengzhou 450011, China;

Received Date: 8 September 2012
Available Online: 3 March 2013
Fund Project: 河南省国际科技合作计划基金(No.124300510050)资助项目。 (No.124300510050)

A new cadmium (Ⅱ) coordination polymer, {[Cd(L)(bpy)(H₂O)₂·2H₂O]}_n(1), was prepared through hydrothermal reaction of Cd(Ⅱ) acetate with H₂L (H₂L=4-methylphthalic acid) and 4,4'-bipyridine. The complex was characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, powder XRD and X-ray single-crystal diffraction. Complex 1 displays a two-dimensional layer, which is further associated through hydrogen bonding to result in a three-dimensional supramolecular architecture. In addition, the luminescence property of the complex 1 was also investigated.
- 4-Methylphthalic acid;hydrogen bonding;supramolecular architecture;luminescence property
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沈阳化工大学材料科学与工程学院沈阳 110142